Journal
CHEMISTRY LETTERS
Volume 41, Issue 10, Pages 1055-1056Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.1055
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Funding
- [GVOP-3.2.1.-2004-04-0210/3.0]
- [OTKA K75182]
- [K101861]
- [FP7-PEOPLE-2010-IRSES-269267]
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Measurements by differential scanning calorimetry (DSC), small-angle neutron scattering (SANS), and H-1 combined rotation and multiple-pulse NMR spectroscopy (CRAMPS) indicate that small aromatic molecules dissolved in poly(N-isopropylacrylamide) (pNIPA) hydrogels modify the temperature of the volume phase transition (TINT) in this system by partially shielding the NIPA side-chains from the water molecules and disrupting their organization. The strength of the interaction increases in the order pyrocatechol < phenol < resorcinol < phloroglucinol.
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