Journal
CHEMISTRY LETTERS
Volume 41, Issue 5, Pages 521-522Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.521
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Funding
- NEDO of Japan
- MEXT, Japan
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Charge-discharge cycling performances of Si thick-film electrodes as Li-ion battery anodes were investigated in several ionic liquids based on bis(fluorosulfonyl)amide (FSA) and bis(trifluoromethanesulfonyl)amide (TFSA) anions. The Si electrodes in FSA-based electrolytes exhibited much better performance than those in TFSA-based electrolytes. An easier desolvation of Li from anions on the electrode surface is probably promoted in FSA-based electrolytes, which enables efficient electrode reactions of Li-insertion/extraction and improvement of cycling performances.
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