Journal
CHEMISTRY LETTERS
Volume 41, Issue 8, Pages 820-821Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2012.820
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Funding
- Japan Society for the Promotion of Science (JSPS) [22245030]
- Grants-in-Aid for Scientific Research [22245030] Funding Source: KAKEN
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Photochemical reaction of a zinc chlorophyll-d derivative possessing a formyl group at the 3-position with a reductant in a deaerated alcoholic solution gave the corresponding 3-unsubstituted chlorin in 43% yield based on consumed starting material. The novel deformylation was accompanied by expected 2,3- or 7,8-dihydrogenation to give minor products possessing a isobacteriochlorin or bacteriochlorin pi-system, respectively, as stereochemical mixtures.
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