4.3 Article

Helicity Induction and Memory of Syndiotactic Poly(methyl methacrylate) Assisted by Optically Active Additives and Solvents and Chiral Amplification of Helicity

Journal

CHEMISTRY LETTERS
Volume 40, Issue 1, Pages 28-30

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2011.28

Keywords

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Funding

  1. Japan Society for the Promotion of Science (JSPS)
  2. Ministry of Education, Culture, Sports, Science and Technology, Japan

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Syndiotactic poly(methyl methacrylate) (st-PMMA) was found to fold into a preferred-handed helix with amplification of helicity assisted by chiral additives and solvents and further encapsulated fullerenes within its helical cavity whose helicity was memorized after removal of the chiral molecules.

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