Journal
CHEMISTRY LETTERS
Volume 39, Issue 11, Pages 1209-1211Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.1209
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) of Japan [20350057]
- Grants-in-Aid for Scientific Research [20350057] Funding Source: KAKEN
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A reactive polymer brush containing alkoxyamine units in the side chains, when heated with an alkoxyamine-terminated fluorinated nongrafted polymer, gave a grafted copolymer brush by a radical crossover reaction of alkoxyamine units The fluorinated grafted copolymer brush could be converted back to the parent polymer brush upon treatment with an excess of low-molecular alkoxyamine The reversible change in the surface properties of the brush was confirmed by X-ray photoelectron spectroscopy and contact angle measurements
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