Journal
CHEMISTRY LETTERS
Volume 39, Issue 10, Pages 1110-1111Publisher
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2010.1110
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Funding
- MEXT [20106001]
- Grants-in-Aid for Scientific Research [20106001, 20106002] Funding Source: KAKEN
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We developed a surface modification of electrospun nonwoven nanofiber mat by surface-initiated atom transfer radical polymerization (ATRP) Nanofibers of poly(methyl methacrylate)-co-poly[2-(2-bromoisobutyryloxy)ethyl methacrylate] were prepared by electrospinning to form a nonwoven nanofiber mat containing bromoalkyl groups, which initiated ATRP of 3-[dimethyl(methacryloyloxyethyl)ammonio]propanesulfonate (DMAPS) and 2-(perfluorooctyl)ethyl acrylate (FA-C-8), respectively, without deformation of nanofiber structure. The surface of the obtained electrospun nonwoven nanofiber mat was characterized by XPS, SEM, AFM, and contact angle measurement before and after surface modification.
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