4.3 Article

Electrolytic properties of ethyl fluoroethyl carbonate and its application to lithium battery

Journal

CHEMISTRY LETTERS
Volume 37, Issue 3, Pages 368-369

Publisher

CHEMICAL SOC JAPAN
DOI: 10.1246/cl.2008.368

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Monofluorination of solvents exerts the strong polar effect on various properties. We have investigated the electrolytic properties of ethyl fluoroethyl carbonate (EFEC) and its application to a lithium battery. Conductivities of EFEC solutions are higher than those of diethyl carbonate (DEC) counterparts above 25 degrees C or below 1 mol dm(-3) of LiPF6. The anodic stability of EFEC is also higher than that of DEC. The use of EFEC as a cosolvent improves the performance of a Li/LiCoO2 coin cell.

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