From linking of metal-oxide building blocks in a dynamic library to giant clusters with unique properties and towards adaptive chemistry

A regioselective Huisgen reaction inside a Keplerate polyoxomolybdate nanoreactor

(2012) Claire Besson et al.   DALTON TRANSACTIONS

Crystallization of a Keplerate-type polyoxometalate into a superposed kagome-lattice with huge channels

(2012) Masaki Saito et al.   DALTON TRANSACTIONS

Encapsulation of Keggin-type anions in reduced molybdenum–iron-type Keplerates as a general phenomenon

(2012) Ana Maria Todea et al.   INORGANICA CHIMICA ACTA

Catalysis in a Porous Molecular Capsule: Activation by Regulated Access to Sixty Metal Centers Spanning a Truncated Icosahedron

(2012) Sivil Kopilevich et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Solution-Phase Monitoring of the Structural Evolution of a Molybdenum Blue Nanoring

(2012) Haralampos N. Miras et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Zen and the art of molecules

(2012) Michelle Francl   Nature Chemistry

Evidence of ionic liquid crystal properties for a DODA+ salt of the keplerate [Mo132O372(CH3COO)30(H2O)72]42−

(2012) Sébastien Floquet et al.   NEW JOURNAL OF CHEMISTRY

Softening of Pore and Interior Properties of a Metal-Oxide-Based Capsule: Substituting 60 Oxide by 60 Sulfide Ligands

(2011) Christian Schäffer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Nanosized Molybdenum Oxide Wheel with a Unique Electronic-Necklace Structure: STM Study with Submolecular Resolution

(2011) Dingyong Zhong et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Modular Redox-Active Inorganic Chemical Cells: iCHELLs

(2011) Geoffrey J. T. Cooper et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Selective conversion of {Mo132} Keplerate ion into 4-electron reduced crown-capped Keggin derivative [Te5Mo15O57]8−. A key intermediate to single-phase M1 multielement MoVTeO light-alkanes oxidation catalyst

(2011) Romain Canioni et al.   CHEMICAL COMMUNICATIONS

Spontaneous self-assembly of a giant spherical metal-oxide Keplerate: addition of one building block induces “immediate” formation of the complementary one from a constitutional dynamic library

(2011) Christian Schäffer et al.   CHEMICAL COMMUNICATIONS

The catalytic role of uranyl in formation of polycatechol complexes

(2011) Prashant Jha et al.   Chemistry Central Journal

Hydrophobic Interactions and Clustering in a Porous Capsule: Option to Remove Hydrophobic Materials from Water

(2011) Christian Schäffer et al.   CHEMISTRY-A EUROPEAN JOURNAL

Reduced Molybenum-Oxide-Based Core-Shell Hybrids: “Blue” Electrons Are Delocalized on the Shell

(2011) Ana Maria Todea et al.   CHEMISTRY-A EUROPEAN JOURNAL

Oxo-Metalate Building Blocks: Conceptual Competitors for Tetravalent Carbon?

(2011) Ira A. Weinstock et al.   ISRAEL JOURNAL OF CHEMISTRY

Polyoxomolybdate-based selective membranes for chemical protection

(2011) Ana Maria Popa et al.   JOURNAL OF MEMBRANE SCIENCE

Dynamics of Encapsulated Water inside Mo132Cavities

(2011) Miquel Garcia-Ratés et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Osmotically Driven Crystal Morphogenesis: A General Approach to the Fabrication of Micrometer-Scale Tubular Architectures Based on Polyoxometalates

(2011) Geoffrey J. T. Cooper et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-Recognition Among Different Polyprotic Macroions During Assembly Processes in Dilute Solution

(2011) T. Liu et al.   SCIENCE

Conical Intersection Dynamics in NO2 Probed by Homodyne High-Harmonic Spectroscopy

(2011) H. J. Worner et al.   SCIENCE

Self-assembly and ion-trapping properties of inorganic nanocapsule-surfactant hybrid spheres

(2011) Haolong Li et al.   Soft Matter

Exploring the mobility of nanoscale polyoxometalates using gel electrophoresis

(2011) Ryo Tsunashima et al.   Chemical Science

Macroporous honeycomb films of surfactant-encapsulated polyoxometalates at air/water interface and their electrochemical properties

(2010) Peiqin Tang et al.   ADVANCES IN COLLOID AND INTERFACE SCIENCE

Guests on Different Internal Capsule Sites Exchange with Each Other and with the Outside

(2010) Olga Petina et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyoxometalates: Building Blocks for Functional Nanoscale Systems

(2010) De-Liang Long et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Biological water: A critique

(2010) Dongping Zhong et al.   CHEMICAL PHYSICS LETTERS

En Route to Nanodevices of Polyoxometalate: Incorporating the Giant Nanoporous Molybdenum-Oxide based Wheels and Balls into Nanotubular Arrays

(2010) Lijuan Zhang et al.   Chemistry-An Asian Journal

Hydrogen-Bond Networks in Water Clusters (H2O)20: An Exhaustive Quantum-Chemical Analysis

(2010) Andrei M. Tokmachev et al.   CHEMPHYSCHEM

Par-delà la synthèse : l’auto-organisation

(2010) Jean-Marie Lehn   COMPTES RENDUS CHIMIE

Self-assembly of dilacunary building blocks into high-nuclear [Ln16As16W164O576(OH)8(H2O)42]80−(Ln = EuIII, GdIII, TbIII, DyIII, and HoIII) polyoxotungstates

(2010) Firasat Hussain et al.   CRYSTENGCOMM

A Supramolecular Derivative of a Nanoporous Molybdenum Oxide Based Inorganic Keplerate with Self-Defocusing Nonlinear Optical Properties

(2010) Lijuan Zhang et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

{Mo96La8} Eggshell Ring and Self-Assembly to {Mo132} Keplerate through Mo-blue Intermediate, Involved in UV-Photolysis of [Mo7O24]6−/Carboxylic Acid System at pH 4

(2010) Toshihiro Yamase et al.   INORGANIC CHEMISTRY

Lipophilic polyoxomolybdate nanocapsules in constitutional dynamic hybrid materials

(2010) Adinela Cazacu et al.   INORGANICA CHIMICA ACTA

Surface modification with multiphilic ligands at detectable well defined active positions of nano-object of giant wheel shaped molybdenum blue showing third-order nonlinear optical properties

(2010) Lijuan Zhang et al.   JOURNAL OF MOLECULAR STRUCTURE

Computational studies of the stability of the (H2O)100 nanodrop

(2010) Annika Lenz et al.   JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM

Water in Cavity−Ligand Recognition

(2010) Riccardo Baron et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-Assembly of a Nanosized, Saddle-Shaped, Solution-Stable Polyoxometalate Anion Built from Pentagonal Building Blocks: [H34W119Se8Fe2O420]54−

(2010) Jun Yan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cellular cation transport studied by 6, 7Li and 23Na NMR in a porous Mo132 Keplerate type nano-capsule as model system

(2010) Dieter Rehder et al.   MAGNETIC RESONANCE IN CHEMISTRY

Polyoxometalate-based functional nanostructured films: Current progress and future prospects

(2010) Shaoqin Liu et al.   Nano Today

Hydrated metal ions in aqueous solution: How regular are their structures?

(2010) Ingmar Persson   PURE AND APPLIED CHEMISTRY

Catalytic properties of the macromolecular polyoxomolybdate cluster in selective oxidation of sulfides

(2010) N. V. Izarova et al.   RUSSIAN CHEMICAL BULLETIN

Unveiling the Transient Template in the Self-Assembly of a Molecular Oxide Nanowheel

(2010) H. N. Miras et al.   SCIENCE

Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic Ring-Shaped Polyoxometalate Cluster

(2009) Shin-ichiro Noro et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Supramolecular Chemistry on a Cluster Surface: Fixation/Complexation of Potassium and Ammonium Ions with Crown-Ether-Like Rings

(2009) Achim Müller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Gadolinium-Bridged Polytungstoarsenate(III) Nanocluster: [Gd8As12W124O432(H2O)22]60���

(2009) Firasat Hussain et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Structural Link between Giant Molybdenum Oxide Based Ions and Derived Keggin Structure: Modular Assemblies Based on the [BW11O39]9−Ion and Pentagonal {M′M5} Units (M′=W; M=Mo,W)

(2009) Nathalie Leclerc-Laronze et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Electronic Control of Spin Coupling in Keplerate-Type Polyoxomolybdates

(2009) Bogdan Botar et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Orthorhombic Mo-V-Sb Oxide Species by Assembly of Pentagonal Mo6O21Polyoxometalate Building Blocks

(2009) Masahiro Sadakane et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Construction of High-Nuclearity Isopolyoxoniobates with Pentagonal Building Blocks: [HNb27O76]16− and [H10Nb31O93(CO3)]23−

(2009) Ryo Tsunashima et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Porous Capsules {(M)M5}12FeIII30 (M=MoVI, WVI): Sphere Surface Supramolecular Chemistry with 20 Ammonium Ions, Related Solution Properties, and Tuning of Magnetic Exchange Interactions

(2009) Ana Maria Todea et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Spherical 24 Butyrate Aggregate with a Hydrophobic Cavity in a Capsule with Flexible Pores: Confinement Effects and Uptake-Release Equilibria at Elevated Temperatures

(2009) Christian Schäffer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Polyoxotungstates now also with pentagonal units: supramolecular chemistry and tuning of magnetic exchange in {(M)M5}12V30 Keplerates (M = Mo, W)

(2009) Ana Maria Todea et al.   CHEMICAL COMMUNICATIONS

Vectorial growth/regulations in a {P8W48}-type polyoxotungstate compartment: trapped unusual molybdenum oxide acts as a handle

(2009) Filipa L. Sousa et al.   CHEMICAL COMMUNICATIONS

Gated and Differently Functionalized (New) Porous Capsules Direct Encapsulates' Structures: Higher and Lower Density Water

(2009) Tamoghna Mitra et al.   CHEMISTRY-A EUROPEAN JOURNAL

Minerals as Molecules-Use of Aqueous Oxide and Hydroxide Clusters to Understand Geochemical Reactions

(2009) William H. Casey et al.   CHEMISTRY-A EUROPEAN JOURNAL

Molybdenum-oxide based unique polyprotic nanoacids showing different deprotonations and related assembly processes in solution

(2009) Melissa L. Kistler et al.   DALTON TRANSACTIONS

Structure-related frustrated magnetism of nanosized polyoxometalates: aesthetics and properties in harmony

(2009) Paul Kögerler et al.   DALTON TRANSACTIONS

Investigation of Intermediates Involved in the Photochemical Formation of Mo-Blue Nanoring by Capillary Electrophoresis–Mass Spectrometry

(2009) Takeru Ito et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Removing Compositional Boundaries in Mixed-Linker Keplerate Clusters

(2009) Bogdan Botar et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Magnetic aligned vesicles

(2009) Dawei Fan et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

Fabrication and Electrocatalytic Properties of Chitosan and Keplerate-Type Polyoxometalate {Mo72Fe30} Hybrid Films

(2009) Dawei Fan et al.   JOURNAL OF PHYSICAL CHEMISTRY B

Structure, Magnetism, and Ionic Conductivity of the Gigantic {Mo176}-Wheel Assembly: Na15Fe3Co16[Mo176O528H3(H2O)80]Cl27·450H2O

(2009) Hiroyuki Imai et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Flexible Pores of a Metal Oxide-Based Capsule Permit Entry of Comparatively Larger Organic Guests

(2009) Ayala Ziv et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Hydrophilic Macroionic Solutions: What Happens When Soluble Ions Reach the Size of Nanometer Scale?

(2009) Tianbo Liu   LANGMUIR

Predicting a structured future

(2009) Achim Müller   Nature Chemistry

Dissolution of insulating oxide materials at the molecular scale

(2009) C. André Ohlin et al.   NATURE MATERIALS

CVD growth of carbon nanotubes using molecular nanoclusters as catalyst

(2009) K. Goss et al.   PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS

Dewetting-Controlled Binding of Ligands to Hydrophobic Pockets

(2009) P. Setny et al.   PHYSICAL REVIEW LETTERS

Racemic crystallography-Easy crystals and easy structures: What's not to like?

(2009) Brian W. Matthews   PROTEIN SCIENCE

Directed 1D Assembly of a Ring-Shaped Inorganic Nanocluster Templated by an Organic Rigid-Rod Molecule: An Inorganic/Organic Polypseudorotaxane

(2008) Md. Akhtarul Alam et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Unprecedented and Differently Applicable Pentagonal Units in a Dynamic Library: A Keplerate of the Type {(W)W5}12{Mo2}30

(2008) Christian Schäffer et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Photoreductive Self-Assembly from [MoVI7O24]6−to Anti-Tumoral [H2MoV12O28(OH)12(MoVIO3)4]6−in Aqueous Media

(2008) Toshihiro Yamase et al.   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN

Azotobacter vinelandii Metal Storage Protein: “Classical” Inorganic Chemistry Involved in Mo/W Uptake and Release Processes

(2008) Jörg Schemberg et al.   CHEMBIOCHEM

Cation behavior at an artificial cell interface: binding distinguished by ion hydration energetics and size

(2008) Alice Merca et al.   CHEMICAL COMMUNICATIONS

Kagome network compounds and their novel magnetic properties

(2008) Swapan K. Pati et al.   CHEMICAL COMMUNICATIONS

Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science

(2008) Anna Proust et al.   CHEMICAL COMMUNICATIONS

Confinement and Step-Wise Reopening of Channels in an Artificial Cell/Inorganic Capsule: A7Li NMR Study

(2008) Erhard T. K. Haupt et al.   CHEMISTRY-A EUROPEAN JOURNAL

Hydrophobic interactions between methane and a nanoscopic pocket: Three dimensional distribution of potential of mean force revealed by computer simulations

(2008) Piotr Setny   JOURNAL OF CHEMICAL PHYSICS

Magnetic {Mo72Fe30}-embedded hybrid nanocapsules

(2008) Jiwei Cui et al.   JOURNAL OF COLLOID AND INTERFACE SCIENCE

The pH Dependent Nuclearity Variation of {Mo154-x}-type Polyoxomolybdates and Tectonic Effect on Their Aggregations

(2008) Sayaka Shishido et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Membranes Based on “Keplerate”-Type Polyoxometalates:  Slow, Passive Cation Transportation and Creation of Water Microenvironment

(2008) Padmaja P. Mishra et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Self-Assembled Monolayer and Multilayer Films of the Nanocluster [HxPMo12O40⊂H4Mo72Fe30(O2CMe)15O254(H2O)68] on Gold

(2008) Ramon Colorado et al.   LANGMUIR

Synthetic Ion Channels via Self-Assembly: A Route for Embedding Porous Polyoxometalate Nanocapsules in Lipid Bilayer Membranes

(2008) Rogan Carr et al.   NANO LETTERS

Quantum oscillations in a molecular magnet

(2008) S. Bertaina et al.   NATURE

Hydrophobicity of protein surfaces: Separating geometry from chemistry

(2008) N. Giovambattista et al.   PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA

Metallo-supramolecular modules as a paradigm for materials science

(2008) Dirk G. Kurth   SCIENCE AND TECHNOLOGY OF ADVANCED MATERIALS

Water in Nonpolar Confinement: From Nanotubes to Proteins and Beyond

(2007) Jayendran C. Rasaiah et al.   Annual Review of Physical Chemistry

Systems chemistry

(2007) R. Frederick Ludlow et al.   CHEMICAL SOCIETY REVIEWS

Surface charges of hedgehog-shaped polyoxomolybdate modified by a cationic surfactant and the inorganic/organic complex

(2007) Peiqin Tang et al.   COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS

The behaviour of in a water nanodrop encapsulated within a highly charged porous metal–oxide nanocontainer: A thermoanalytical study

(2007) Adam Bielański et al.   INORGANIC CHEMISTRY COMMUNICATIONS

Nanoscale Assemblies of Gigantic Molecular {Mo154}-Rings:  (Dimethyldioctadecylammonium)20[Mo154O462H8(H2O)70]

(2007) Tomoyuki Akutagawa et al.   LANGMUIR