Rhodium-catalyzed acyloxy migration of propargylic esters in cycloadditions, inspiration from the recent “gold rush”

Rhodium-catalyzed 1,3-acyloxy migration and subsequent intramolecular [4+2] cycloaddition of vinylallene and unactivated alkyne

(2012) Suyu Huang et al.   CHEMICAL COMMUNICATIONS

Factors Controlling the Equilibrium of Pt-Catalyzed [1,2]- versus [1,3]-Acyloxy Migration

(2012) Eun Jin Cho   CHEMISTRY-A EUROPEAN JOURNAL

Rh-Catalyzed [5+1] and [4+1] Cycloaddition Reactions of 1,4-Enyne Esters with CO: A Shortcut to Functionalized Resorcinols and Cyclopentenones

(2012) Takahide Fukuyama et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Intra- and Intermolecular [5 + 2] Cycloaddition of 3-Acyloxy-1,4-enyne and Alkyne with Concomitant 1,2-Acyloxy Migration

(2012) Xing-Zhong Shu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh(I)-Catalyzed [5 + 1] Cycloaddition of Vinylcyclopropanes and CO for the Synthesis of α,β- and β,γ-Cyclohexenones

(2012) Guo-Jie Jiang et al.   ORGANIC LETTERS

Rhodium-Catalyzed Carbonylation of 3-Acyloxy-1,4-enynes for the Synthesis of Cyclopentenones

(2012) Xiaoxun Li et al.   ORGANIC LETTERS

Interception of a Rautenstrauch Intermediate by Alkynes for [5+2] Cycloaddition: Rhodium-Catalyzed Cycloisomerization of 3-Acyloxy-4-ene-1,9-diynes to Bicyclo[5.3.0]decatrienes

(2011) Xing-zhong Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Ring Expansion of Cyclopropanes to Seven-membered Rings by 1,5 CC Bond Migration

(2011) Xiaoxun Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed [3+2] Cycloaddition/Hydrolytic Michael Addition/Retro-Aldol Reactions of Propargylic Esters Tethered to Cyclohexadienones

(2011) Shunyou Cai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent developments in gold-catalyzed cycloaddition reactions

(2011) Fernando López et al.   Beilstein Journal of Organic Chemistry

Gold catalysis in total synthesis—an update

(2011) Matthias Rudolph et al.   CHEMICAL SOCIETY REVIEWS

Gold(I)-Catalyzed Reactions of Propargyl Esters with Vinyl Derivatives

(2011) Christian A. Sperger et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Chiral (Acyclic Diaminocarbene)Gold(I)-Catalyzed Dynamic Kinetic Asymmetric Transformation of Propargyl Esters

(2011) Yi-Ming Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Tandem 1,3-Migration/[2 + 2] Cycloaddition of 1,7-Enyne Benzoates to Azabicyclo[4.2.0]oct-5-enes

(2011) Weidong Rao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Au-Catalyzed Piperidine Synthesis via Tandem Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters

(2011) Huaiji Zheng et al.   ORGANIC LETTERS

Synthesis of Highly Functionalized Cyclohexenone Rings: Rhodium-Catalyzed 1,3-Acyloxy Migration and Subsequent [5+1] Cycloaddition

(2010) Dongxu Shu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Gold-Catalyzed Cyclopenta- and Cycloheptannulation Cascades: A Stereocontrolled Approach to the Scaffold of Frondosins A and B

(2010) David Garayalde et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The use of Br/Cl to promote regioselective gold-catalyzed rearrangement of propargylic carboxylates: an efficient synthesis of (1Z, 3E)-1-bromo/chloro-2-carboxy-1,3-dienes

(2010) Yanzhao Wang et al.   CHEMICAL COMMUNICATIONS

Synthesis of functionalized resorcinols by rhodium-catalyzed [5+1] cycloaddition reaction of 3-acyloxy-1,4-enynes with CO

(2010) Célia Brancour et al.   CHEMICAL COMMUNICATIONS

Theoretical studies of regioselectivity of Ni- and Rh-catalyzed C–C bond forming reactions with unsymmetrical alkynes

(2010) Peng Liu et al.   INORGANICA CHIMICA ACTA

Cationic Rhodium(I) Complex-Catalyzed [3 + 2] and [2 + 1] Cycloadditions of Propargyl Esters with Electron-Deficient Alkynes and Alkenes

(2010) Yu Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pt-Catalyzed Tandem 1,2-Acyloxy Migration/Intramolecular [3 + 2] Cycloaddition of Enynyl Esters

(2010) Huaiji Zheng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Mechanistic Insights in Gold-Stabilized Nonclassical Carbocations: Gold-Catalyzed Rearrangement of 3-Cyclopropyl Propargylic Acetates

(2010) David Garayalde et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed Stereocontrolled Oxacyclization/[4+2]-Cycloaddition Cascade of Ketone-Allene Substrates

(2010) Tse-Min Teng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Rh-Catalyzed [7 + 1] Cycloaddition of Buta-1,3-dienylcyclopropanes and CO for the Synthesis of Cyclooctadienones

(2010) Zhong-Ke Yao et al.   ORGANIC LETTERS

Gold-catalyzed intermolecular [4C+3C] cycloaddition reactions

(2010) Benjamin W. Gung et al.   TETRAHEDRON LETTERS

Gold- and Platinum-Catalyzed Cycloisomerization of Enynyl Esters versus Allenenyl Esters: An Experimental and Theoretical Study

(2009) Nicolas Marion et al.   CHEMISTRY-A EUROPEAN JOURNAL

Synthesis of (−)-Cubebol by Face-Selective Platinum-, Gold-, or Copper-Catalyzed Cycloisomerization: Evidence of Chirality Transfer and Mechanistic Insights

(2009) Charles Fehr et al.   CHEMISTRY-A EUROPEAN JOURNAL

Mechanistic Studies on Au(I)-Catalyzed [3,3]-Sigmatropic Rearrangements using Cyclopropane Probes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation

(2009) Iain D. G. Watson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [3+3]-Annulation of Azomethine Imines with Propargyl Esters

(2009) Nathan D. Shapiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The Meyer–Schuster rearrangement for the synthesis of α,β-unsaturated carbonyl compounds

(2009) Douglas A. Engel et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Synthesis of Cyclobutenes by Highly Selective Transition-Metal-Catalyzed Ring Expansion of Cyclopropanes

(2008) Huadong Xu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

New Insights on the Mechanism of the Transition-Metal Stereoselective Olefin Cyclopropanation

(2008) Elena Soriano et al.   CHEMISTRY-A EUROPEAN JOURNAL

A Gold-Catalyzed Entry into the Sesquisabinene and Sesquithujene Families of Terpenoids and Formal Total Syntheses of Cedrene and Cedrol

(2008) Alois Fürstner et al.   CHEMISTRY-A EUROPEAN JOURNAL

Platinum-Catalyzed Cycloisomerization Reaction of 1,6-Enyne Coupling with Rearrangement of Propargylic Esters

(2008) Li Lu et al.   JOURNAL OF ORGANIC CHEMISTRY

Fluorenes and Styrenes by Au(I)-Catalyzed Annulation of Enynes and Alkynes

(2008) David J. Gorin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Synthesis of Azepines by a Gold-Catalyzed Intermolecular [4 + 3]-Annulation

(2008) Nathan D. Shapiro et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in syntheses of carbocycles and heterocycles via homogeneous gold catalysis. Part 2: Cyclizations and cycloadditions

(2008) Hong C. Shen   TETRAHEDRON

Golden Carousel in Catalysis: The Cationic Gold/Propargylic Ester Cycle

(2007) Andrea Correa et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION