Enantioselective, transition metal catalyzed cycloisomerizations

Enantioselective Cyclizations of Silyloxyenynes Catalyzed by Cationic Metal Phosphine Complexes

(2012) Jean-François Brazeau et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Cyclometalated N-Heterocyclic Carbene-Platinum Catalysts for the Enantioselective Cycloisomerization of Nitrogen-Tethered 1,6-Enynes

(2011) Hélène Jullien et al.   ADVANCED SYNTHESIS & CATALYSIS

Rhodium-Catalyzed Enantioselective Intramolecular [4+2] Cycloaddition using a Chiral Phosphine-Phosphite Ligand: Importance of Microwave-Assisted Catalyst Conditioning

(2011) Anna Falk et al.   ADVANCED SYNTHESIS & CATALYSIS

Recent Developments in the [5+2] Cycloaddition

(2011) Hélène Pellissier   ADVANCED SYNTHESIS & CATALYSIS

Enantioselective Gold(I)-Catalyzed Intramolecular (4+3) Cycloadditions of Allenedienes

(2011) Isaac Alonso et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Enantioselective Intramolecular Hydroarylation of Alkynes To Form Axially Chiral 4-Aryl 2-Quinolinones

(2011) Tetsuro Shibuya et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Rhodium-Catalyzed Allylic CH Activation for the Addition to Conjugated Dienes

(2011) Qian Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cationic gold(I) axially chiral biaryl bisphosphine complex-catalyzed atropselective synthesis of heterobiaryls

(2011) Tetsuro Shibuya et al.   Beilstein Journal of Organic Chemistry

Transition Metal Catalyzed Cycloisomerizations of 1,n-Allenynes and -Allenenes

(2011) Corinne Aubert et al.   CHEMICAL REVIEWS

Gold-Catalyzed Nucleophilic Cyclization of Functionalized Allenes: A Powerful Access to Carbo- and Heterocycles

(2011) Norbert Krause et al.   CHEMICAL REVIEWS

Recent advances in [2+2+2] cycloaddition reactions

(2011) Gema Domínguez et al.   CHEMICAL SOCIETY REVIEWS

Enantioselective IrI-Catalyzed Carbocyclization of 1,6-Enynes by the Chiral Counterion Strategy

(2011) Marion Barbazanges et al.   CHEMISTRY-A EUROPEAN JOURNAL

Concise Synthesis of the Antidepressive Drug Candidate GSK1360707 by a Highly Enantioselective Gold-Catalyzed Enyne Cycloisomerization Reaction

(2011) Henrik Teller et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Cycloisomerization of 1,5-Enynes Promoted by Cyclometalated NHC-PtII-Monophos Catalysts

(2011) Hélène Jullien et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Phosphoramidite Gold(I)-Catalyzed Diastereo- and Enantioselective Synthesis of 3,4-Substituted Pyrrolidines

(2011) Ana Z. González et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Rh(I)-Catalyzed Intramolecular [3 + 2] Cycloaddition of 1-Yne-vinylcyclopropanes for Bicyclo[3.3.0] Compounds with a Chiral Quaternary Carbon Stereocenter and Density Functional Theory Study of the Origins of Enantioselectivity

(2011) Mu Lin et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Highly Reusable Rhodium Catalyst-Organic Framework for the Intramolecular Cycloisomerization of 1,6-Enynes

(2011) Elizabeth G. Corkum et al.   ORGANIC LETTERS

Rhodium-Catalyzed Olefin Isomerization/Enantioselective Intramolecular Alder-Ene Reaction Cascade

(2011) Ryuichi Okamoto et al.   ORGANIC LETTERS

Chiral Diene-Phosphine Tridentate Ligands for Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes

(2011) Takahiro Nishimura et al.   ORGANIC LETTERS

RhCl(PPh3)3-Catalyzed Intramolecular Cycloaddition of Enediynes: The Nature of the Tether and Substituents Controls the Reaction Mechanism

(2011) Anna Dachs et al.   ORGANOMETALLICS

Gold(I)-Catalyzed Enantioselective Synthesis of Functionalized Indenes

(2010) Alberto Martínez et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Gold Catalysis: Opportunities Provided by Monodentate Phosphoramidite Ligands with an Acyclic TADDOL Backbone

(2010) Henrik Teller et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Chiral Tetrafluorobenzobarrelene Ligands for the Rhodium-Catalyzed Asymmetric Cycloisomerization of Oxygen- and Nitrogen-Bridged 1,6-Enynes

(2010) Takahiro Nishimura et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Recent Advances in Asymmetric Gold Catalysis

(2010) Sujata Sengupta et al.   ChemCatChem

Chiral Cationic Platinum Complexes: New Catalysts for The Activation of Carbon-Carbon Multiple Bonds Towards Nucleophilic Enantioselective Attack

(2010) Patrick Y. Toullec et al.   CURRENT ORGANIC CHEMISTRY

Concise and Enantioselective Total Synthesis of 15-Deoxy-Δ12,14-Prostaglandin J2

(2010) Nam-Jung Kim et al.   JOURNAL OF ORGANIC CHEMISTRY

An Enyne Cycloisomerization Approach to the Triple Reuptake Inhibitor GSK1360707F

(2010) Nicole M. Deschamps et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Intramolecular [2+2+2] Cycloaddition of Dienynes for the Construction of Adjacent Three Chiral Centers

(2010) Takanori Shibata et al.   SYNLETT

Chiral N-phosphino sulfinamide ligands in rhodium(I)-catalyzed [2+2+2] cycloaddition reactions

(2010) Sandra Brun et al.   TETRAHEDRON

Mechanistic Insights on the Cycloisomerization of Polyunsaturated Precursors Catalyzed by Platinum and Gold Complexes

(2009) Elena Soriano et al.   ACCOUNTS OF CHEMICAL RESEARCH

Novel Enantioselective Sequentially Rhodium(I)/BINAP- Catalyzed Cycloisomerization–Hydrogenation–Isomerization– Acetalization (CIHIA)

(2009) Nadine Körber et al.   ADVANCED SYNTHESIS & CATALYSIS

One-Step Construction of Five Successive Rings by Rhodium-Catalyzed Intermolecular Double [2+2+2] Cycloaddition: Enantioenriched [9]Helicene-Like Molecules

(2009) Ken Tanaka et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium-Catalyzed Asymmetric Enyne Cycloisomerization of Terminal Alkynes and Formal Total Synthesis of (−)-Platensimycin

(2009) K. C. Nicolaou et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Rhodium catalyzed enantioselective cyclization of substituted imidazoles via C–H bond activation

(2009) Andy S. Tsai et al.   CHEMICAL COMMUNICATIONS

Asymmetric Au(i)-catalyzed synthesis of bicyclo[4.1.0]heptene derivatives via a cycloisomerization process of 1,6-enynes

(2009) Chung-Meng Chao et al.   CHEMICAL COMMUNICATIONS

Transition metal-catalyzed C–H activation reactions: diastereoselectivity and enantioselectivity

(2009) Ramesh Giri et al.   CHEMICAL SOCIETY REVIEWS

Gold and platinum catalysis—a convenient tool for generating molecular complexity

(2009) Alois Fürstner   CHEMICAL SOCIETY REVIEWS

Exploiting [2+2] cycloaddition chemistry: achievements with allenes

(2009) Benito Alcaide et al.   CHEMICAL SOCIETY REVIEWS

Synthesis of (−)-Cubebol by Face-Selective Platinum-, Gold-, or Copper-Catalyzed Cycloisomerization: Evidence of Chirality Transfer and Mechanistic Insights

(2009) Charles Fehr et al.   CHEMISTRY-A EUROPEAN JOURNAL

Rhodium-Catalyzed Asymmetric [5+2] Cycloaddition of Alkyne-Vinylcyclopropanes

(2009) Ryo Shintani et al.   CHEMISTRY-A EUROPEAN JOURNAL

Gold Catalysis: Enantiotopos Selection

(2009) A. Stephen K. Hashmi et al.   CHEMISTRY-A EUROPEAN JOURNAL

Silver and Gold Catalysis for Cycloisomerization Reactions

(2009) Philippe Belmont et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Gold(I)-Catalyzed Enantioselective Synthesis of BenzopyransviaRearrangement of Allylic Oxonium Intermediates

(2009) Minoru Uemura et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Ligand-Controlled Access to [4 + 2] and [4 + 3] Cycloadditions in Gold-Catalyzed Reactions of Allene-Dienes

(2009) Pablo Mauleón et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of Platensimycin and Related Natural Products

(2009) K. C. Nicolaou et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Asymmetric Synthesis of Medium-Sized Rings by Intramolecular Au(I)-Catalyzed Cyclopropanation

(2009) Iain D. G. Watson et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Gold-Catalyzed [4C+2C] Cycloadditions of Allenedienes, including an Enantioselective Version with New Phosphoramidite-Based Catalysts: Mechanistic Aspects of the Divergence between [4C+3C] and [4C+2C] Pathways

(2009) Isaac Alonso et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Construction of Axial Chirality by Palladium-Catalyzed Cycloisomerization ofN-Alkenyl Arylethynylamides

(2009) Hidetomo Imase et al.   ORGANIC LETTERS

Platinum(II) Catalysts for Highly Enantioselective 1,6-Enyne Cycloisomerizations. Synthetic, Structural, and Catalytic Studies

(2009) Delphine Brissy et al.   ORGANIC LETTERS

Enantioselective Synthesis of Chiral Tripodal Cage Compounds by [2 + 2 + 2] Cycloaddition of Branched Triynes

(2009) Takanori Shibata et al.   ORGANIC LETTERS

Gold(I)-Catalyzed Enantioselective [4 + 2]-Cycloaddition of Allene-dienes

(2009) Ana Z. González et al.   ORGANIC LETTERS

Stereoselective Nickel-Catalyzed Cycloisomerization of 1,6-Dienes

(2008) Christian Böing et al.   ADVANCED SYNTHESIS & CATALYSIS

Cycloisomerization of 1,n-Enynes: Challenging Metal-Catalyzed Rearrangements and Mechanistic Insights

(2008) Véronique Michelet et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Highly Strained Planar-Chiral Platinacycle for Catalytic Activation of Internal Olefins in the Friedel-Crafts Alkylation of Indoles

(2008) Haoxi Huang et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Fused tetracycles with a benzene or cyclohexadiene core: [2 + 2 + 2] cycloadditions on macrocyclic systems

(2008) Sandra Brun et al.   CHEMICAL COMMUNICATIONS

Rhodium-catalyzed enantio- and diastereoselective intramolecular [2 + 2 + 2] cycloaddition of unsymmetrical dienynes

(2008) Hiromi Sagae et al.   CHEMICAL COMMUNICATIONS

Catalytic skeletal reorganization of enynes through electrophilicactivation of alkynes: double cleavage of C–C double and triple bonds

(2008) Sang Ick Lee et al.   CHEMICAL COMMUNICATIONS

Ligand Effects in Homogeneous Au Catalysis

(2008) David J. Gorin et al.   CHEMICAL REVIEWS

Gold-Catalyzed Cycloisomerizations of Enynes: A Mechanistic Perspective

(2008) Eloísa Jiménez-Núñez et al.   CHEMICAL REVIEWS

Recent Developments in Enantioselective Gold(I) Catalysis

(2008) Ross A. Widenhoefer   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Intramolecular Hydroarylation of Alkenes via Directed C−H Bond Activation

(2008) Hitoshi Harada et al.   JOURNAL OF ORGANIC CHEMISTRY

Enantioselective Syntheses of Various Chiral Multicyclic Compounds with Quaternary Carbon Stereocenters by Catalytic Intramolecular Cycloaddition

(2008) Takanori Shibata et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Recent advances in enantioselective [2 + 2 + 2] cycloaddition

(2008) Takanori Shibata et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Au(I)-Catalyzed Ring Expanding Cycloisomerizations: Total Synthesis of Ventricosene

(2008) Steven G. Sethofer et al.   ORGANIC LETTERS

Platinum(II) Complexes Featuring Chiral Diphosphines and N-Heterocyclic Carbene Ligands: Synthesis and Evaluation as Cycloisomerization Catalysts

(2008) Delphine Brissy et al.   ORGANOMETALLICS

Iridium-catalyzed consecutive and enantioselective [2+2+2] cycloaddition of tetraynes and hexaynes for the construction of an axially chiral biaryl system

(2007) Takanori Shibata et al.   TETRAHEDRON

Enantioselective synthesis of planar-chiral metacyclophanes through cationic Rh(I)/modified-BINAP-catalyzed inter- and intramolecular alkyne cyclotrimerizations

(2007) Ken Tanaka et al.   TETRAHEDRON