The N-heterocyclic carbene chemistry of transition-metal carbonyl clusters

Different Reactivities of Pyrid-2-yl- and 6-Picol-2-yl-Functionalized NHC Ligands with [Ru3(CO)12]: C(sp2)−H and Double C(sp3)−H Bond Activation Reactions

(2011) Javier A. Cabeza et al.   ORGANOMETALLICS

Reactivity of Cationic Triruthenium Carbonyl Clusters: From Pyrimidinium Ligands to N-Heterocyclic Carbenes

(2011) Javier A. Cabeza et al.   ORGANOMETALLICS

Reactivity of [Ru3(CO)12] with a Phosphine-Functionalized Imidazol-2-ylidene and Its Imidazolium Salt

(2011) Javier A. Cabeza et al.   ORGANOMETALLICS

Palladium Catalysts with Sulfonate-Functionalized-NHC Ligands for Suzuki−Miyaura Cross-Coupling Reactions in Water

(2011) Fernando Godoy et al.   ORGANOMETALLICS

The Development and Catalytic Uses of N-Heterocyclic Carbene Gold Complexes

(2010) Steven P. Nolan   ACCOUNTS OF CHEMICAL RESEARCH

Sulfonated N-Heterocyclic Carbenes for Pd-Catalyzed Sonogashira and Suzuki-Miyaura Coupling in Aqueous Solvents

(2010) Sutapa Roy et al.   ADVANCED SYNTHESIS & CATALYSIS

Stable Cyclic Carbenes and Related Species beyond Diaminocarbenes

(2010) Mohand Melaimi et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Beginnings of N-Heterocyclic Carbenes

(2010) Wolfgang Kirmse   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

The Measure of All Rings-N-Heterocyclic Carbenes

(2010) Thomas Dröge et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Percent buried volume for phosphine and N-heterocyclic carbene ligands: steric properties in organometallic chemistry

(2010) Hervé Clavier et al.   CHEMICAL COMMUNICATIONS

A simple, general route to 2-pyridylidene transition metal complexes

(2010) Marta Roselló-Merino et al.   CHEMICAL COMMUNICATIONS

Beyond catalysis: N-heterocyclic carbene complexes as components for medicinal, luminescent, and functional materials applications

(2010) Laszlo Mercs et al.   CHEMICAL SOCIETY REVIEWS

N-Heterocyclic Carbene Mediated Activation of Tetravalent Silicon Compounds: A Critical Evaluation

(2010) Matthew J. Fuchter   CHEMISTRY-A EUROPEAN JOURNAL

Reductive Dimerization of Triruthenium Clusters Containing Cationic Aromatic N-Heterocyclic Ligands

(2010) Javier A. Cabeza et al.   CHEMISTRY-A EUROPEAN JOURNAL

Triazole-Functionalized N-Heterocyclic Carbene Complexes of Palladium and Platinum and Efficient Aqueous Suzuki-Miyaura Coupling Reaction

(2010) Shaojin Gu et al.   Chemistry-An Asian Journal

N-Heterocyclic carbene–rhodium complexes as catalysts for hydroformylation and related reactions

(2010) W. Gil et al.   COORDINATION CHEMISTRY REVIEWS

Sulfur-functionalized N-heterocyclic carbenes and their transition metal complexes

(2010) Matthias Bierenstiel et al.   COORDINATION CHEMISTRY REVIEWS

A robust hydrophilic pyridine-bridged bis-benzimidazolylidene palladium pincer complex: Synthesis and its catalytic application towards Suzuki–Miyaura couplings in aqueous solvents

(2010) Tao Tu et al.   DALTON TRANSACTIONS

Effect of substituents at the heteroatom on the structure and ligating properties of heterocyclic carbene, silylene, germylene and abnormal carbene: A theoretical study

(2010) Ankur Kanti Guha et al.   DALTON TRANSACTIONS

Fascinating frontiers of N/O-functionalized N-heterocyclic carbene chemistry: from chemical catalysis to biomedical applications

(2010) Alex John et al.   DALTON TRANSACTIONS

NHC - Ligand der Ideen

(2010) Thomas Dröge et al.   NACHRICHTEN AUS DER CHEMIE

From Allenes to Edge-Bridging Allyl Ligands or Face-Capping Alkenyl Ligands on a Triruthenium Hydrido Carbonyl Cluster: An Experimental and DFT Computational Study†

(2010) Javier A. Cabeza et al.   ORGANOMETALLICS

Reactivity of [Os3(μ-H)2(CO)10] with N-Heterocyclic Carbenes: A Combined Experimental and DFT Computational Study§

(2010) Javier A. Cabeza et al.   ORGANOMETALLICS

Phthalazin-2-ylidenes As Cyclic Amino Aryl Carbene Ligands in Rhodium(I) and Iridium(I) Complexes

(2010) Antonio Magriz et al.   ORGANOMETALLICS

Glucopyranoside-Incorporated N-Heterocyclic Carbene Complexes of Silver(I) and Palladium(II): Efficient Water-Soluble Suzuki−Miyaura Coupling Palladium(II) Catalysts

(2010) Chien-Chan Yang et al.   ORGANOMETALLICS

Trapping of Pyrid-2-ylidenes by [Ru3(CO)12]: Orthometalated Pyrid-2-ylidenes in Triruthenium Clusters

(2010) Javier A. Cabeza et al.   ORGANOMETALLICS

Mixed N-heterocyclic carbene and phosphine palladium complexes for telomerization of butadiene with methanol

(2009) Julien Mesnager et al.   APPLIED CATALYSIS A-GENERAL

Ruthenium-Based Olefin Metathesis Catalysts BearingN-Heterocyclic Carbene Ligands

(2009) Cezary Samojłowicz et al.   CHEMICAL REVIEWS

Complexes with Poly(N-heterocyclic carbene) Ligands: Structural Features and Catalytic Applications

(2009) Macarena Poyatos et al.   CHEMICAL REVIEWS

N-Heterocyclic Carbenes in Late Transition Metal Catalysis

(2009) Silvia Díez-González et al.   CHEMICAL REVIEWS

Beyond ConventionalN-Heterocyclic Carbenes: Abnormal, Remote, and Other Classes of NHC Ligands with Reduced Heteroatom Stabilization

(2009) Oliver Schuster et al.   CHEMICAL REVIEWS

Coinage Metal−N-Heterocyclic Carbene Complexes

(2009) Joseph C. Y. Lin et al.   CHEMICAL REVIEWS

Ruthenium-Based Heterocyclic Carbene-Coordinated Olefin Metathesis Catalysts†

(2009) Georgios C. Vougioukalakis et al.   CHEMICAL REVIEWS

Cationic Heterocycles as Ligands: Synthesis and Reactivity with Anionic Nucleophiles of Cationic Triruthenium Clusters Containing C-MetalatedN-Methylquinoxalinium orN-Methylpyrazinium Ligands

(2009) Javier A. Cabeza et al.   CHEMISTRY-A EUROPEAN JOURNAL

Quinobis(imidazolylidene): Synthesis and Study of an Electron-Configurable Bis(N-Heterocyclic Carbene) and Its Bimetallic Complexes

(2009) Andrew G. Tennyson et al.   CHEMISTRY-A EUROPEAN JOURNAL

Sawhorse-type diruthenium tetracarbonyl complexes

(2009) Bruno Therrien et al.   COORDINATION CHEMISTRY REVIEWS

Reactions of indenyl-functionalized imidazolium salts and N-heterocyclic carbenes with Ru3(CO)12

(2009) Congying Zhang et al.   DALTON TRANSACTIONS

Aqueous-phase Suzuki–Miyaura cross-coupling reactions catalyzed by Pd-NHC complexes

(2009) Hayati Türkmen et al.   DALTON TRANSACTIONS

Mono-, Bi- and Tridentate N-Heterocyclic Carbene Ligands for the Preparation of Transition-Metal-Based Homogeneous Catalysts

(2009) Rosa Corberán et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Six- and seven-membered ring carbenes: Rational synthesis of amidinium salts, generation of carbenes, synthesis of Ag(I) and Cu(I) complexes

(2009) Eugene L. Kolychev et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Synthesis and structural characterisation of the palladium N-heterocyclic carbene cluster complexes [Pd3(μ-CO)3(NHC)3] and [Pd3(μ-SO2)3(NHC)3]

(2009) Charles E. Ellul et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

A Modular Synthesis of Highly Substituted Imidazolium Salts

(2009) Keiichi Hirano et al.   ORGANIC LETTERS

Reactivity of [Ru4(μ-H)4(CO)12] with N-Heterocyclic Carbenes

(2009) Javier A. Cabeza et al.   ORGANOMETALLICS

Reactivity of Protons, Tertiary Stannanes, and Alkynes with a Triruthenium Dihydrido Cluster Containing a Face-Capping NHC Ligand

(2009) Javier A. Cabeza et al.   ORGANOMETALLICS

DFT Mechanistic Study of the Transformation of Cyclohexa-1,3-diene into a Bridging Allyl Ligand upon Reaction with a Triruthenium Hydrido Carbonyl Cluster

(2009) Javier A. Cabeza et al.   ORGANOMETALLICS

Tolman’s Electronic Parameters for Divalent Carbon(0) Compounds

(2009) Ralf Tonner et al.   ORGANOMETALLICS

Topological Analysis of the Electron Density in the N-Heterocyclic Carbene Triruthenium Cluster [Ru3(μ-H)2(μ3-MeImCH)(CO)9] (Me2Im = 1,3-dimethylimidazol-2-ylidene)

(2009) Javier A. Cabeza et al.   ORGANOMETALLICS

Electronic and Steric Parameters of 76 N-Heterocyclic Carbenes in Ni(CO)3(NHC)

(2009) Dmitry G. Gusev   ORGANOMETALLICS

From anN-Methyl N-Heterocyclic Carbene to Carbyne and Carbide Ligands via Multiple CH and CN Bond Activations

(2008) Javier A. Cabeza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Heterocyclic Carbenes: Synthesis and Coordination Chemistry

(2008) F. Ekkehardt Hahn et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A Simple Preparation of Pyridine-Derived N-Heterocyclic Carbenes and Their Transformation into Bridging Ligands by Orthometalation

(2008) Javier A. Cabeza et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

C4-bound imidazolylidenes: from curiosities to high-impact carbene ligands

(2008) Martin Albrecht   CHEMICAL COMMUNICATIONS

Carbenes: Synthesis, properties, and organometallic chemistry

(2008) Pierre de Frémont et al.   COORDINATION CHEMISTRY REVIEWS

Activation of two C–H bonds of NHC N-methyl groups on triosmium and triruthenium carbonyl clusters

(2008) Javier A. Cabeza et al.   DALTON TRANSACTIONS

Unsaturated dinickel–molybdenum clusters with N-heterocyclic carbene ligands

(2008) Sandra Milosevic et al.   DALTON TRANSACTIONS

The reactivity of N-heterocyclic carbenes and their precursors with [Ru3(CO)12]

(2008) Michael I. Bruce et al.   DALTON TRANSACTIONS

Abnormal coordination of Arduengo's carbene upon reaction with M3(CO)12 (M = Ru, Os)

(2008) Matthew R. Crittall et al.   DALTON TRANSACTIONS

Donor-Functionalised N-Heterocyclic Carbene Complexes of Group 9 and 10 Metals in Catalysis: Trends and Directions

(2008) Adrien T. Normand et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

Acceptor substituted N-heterocyclic carbenes and their Rh(I)complexes: Synthesis, structure and properties

(2008) Agnes Bittermann et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Ruthenium–tin complexes from the reaction of HSnPh3 with Ru3(CO)10(NCMe)2 and their reactions with bis(tri-t-butylphosphine)platinum

(2008) Richard D. Adams et al.   JOURNAL OF ORGANOMETALLIC CHEMISTRY

Double C−H Bond Activation of an NHC N-Methyl Group on Triruthenium and Triosmium Carbonyl Clusters: A DFT Mechanistic Study

(2008) Javier A. Cabeza et al.   ORGANOMETALLICS

NHC Complexes of Osmium Clusters: A Structural and Reactivity Study

(2008) Craig E. Cooke et al.   ORGANOMETALLICS

Basal-Edge-Bridged Square-Pyramidal Hexaruthenium Carbonyl Clusters: Synthesis, Structure, and Reactivity

(2008) Javier A. Cabeza et al.   ORGANOMETALLICS

Rhodium and Iridium Complexes of Abnormal N-Heterocyclic Carbenes Derived from Imidazo[1,2-a]pyridine

(2008) Guoyong Song et al.   ORGANOMETALLICS

N-Heterocyclic carbenes: deducing σ- and π-contributions in Rh-catalyzed hydroboration and Pd-catalyzed coupling reactions

(2008) Dimitri M. Khramov et al.   TETRAHEDRON

N-Heterocyclic carbeneligands bearing hydrophilic and/or hydrophobic chains: Rh(i) and Pd(ii) complexes and their catalytic activity

(2007) Hidetoshi Ohta et al.   DALTON TRANSACTIONS

One-N, six-membered heterocyclic carbene complexes and the remote heteroatom concept

(2007) Helgard G. Raubenheimer et al.   DALTON TRANSACTIONS

Cleavage of Ru3(CO)12by N-Heterocyclic Carbenes: Isolation ofcis- andtrans-Ru(NHC)2(CO)3and Reaction with O2To Form Ru(NHC)2(CO)2(CO3)

(2007) Charles E. Ellul et al.   ORGANOMETALLICS

Reactivity of N-Heterocyclic Carbenes with [Ru3(CO)12] and [Os3(CO)12]. Influence of Ligand Volume and Electronic Effects

(2007) Javier A. Cabeza et al.   ORGANOMETALLICS

Determination of N-Heterocyclic Carbene (NHC) Steric and Electronic Parameters using the [(NHC)Ir(CO)2Cl] System

(2007) Roy A. Kelly III et al.   ORGANOMETALLICS