Journal
CHEMICAL PHYSICS LETTERS
Volume 515, Issue 1-3, Pages 23-28Publisher
ELSEVIER
DOI: 10.1016/j.cplett.2011.08.089
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Funding
- Department of Science and Technology (DST), Government of India [SR/FT/CS-029/2009]
- Council of Scientific and Industrial Research (CSIR)
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The solvent relaxation and rotational dynamics of coumarin 153 and 4-aminophthalimide have been investigated in a hydrophobic room-temperature ionic liquid, 1-(2-methoxyethyl)-1-methylpyrrolidinium tris(pentafluoroethyl)trifluorophosphate. The dynamic fluorescence Stokes shift measurements suggest that the average solvation time is highly dependent on the probe molecules. The average solvation time of 4-aminophthalimide is estimated to be six times larger than that of coumarin 153. Rotational coupling constant value of 4-aminophthalimide is also found to be larger than that of coumarin 153. Hydrogen bonding interaction between the probe molecule (4-aminophthalimide) and the ionic liquid is found to play a role on the dynamics of solvation in the present medium. (C) 2011 Elsevier B.V. All rights reserved.
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