Journal
CHEMICAL PHYSICS LETTERS
Volume 464, Issue 4-6, Pages 192-197Publisher
ELSEVIER SCIENCE BV
DOI: 10.1016/j.cplett.2008.09.016
Keywords
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Funding
- Swedish Research Council
- Swedish Energy Agency
- Goran Gustafsson Foundation
- Carl Trygger Foundation
- Swedish Foundation for Strategic Research
- Knut and Alice Wallenberg foundation
- EU [CT-2004-506008]
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The valence electronic structure of a series of molecular films containing ruthenium polypyridine complexes has been investigated by photoelectron spectroscopy (PES) at high kinetic energy (HIKE) using hard X-ray. The experiment shows the possibility to experimentally probe the metal contribution to the valence spectra in a bulk sensitive mode. Specifically to directly follow the Ru 4d contribution to the highest occupied molecular orbitals of such complexes. The experimental spectra are accurately modeled by DFT calculations only if a crystal structure environment is taken into account showing the importance of intermolecular interaction for modeling the electronic structure of such complexes. (C) 2008 Elsevier B.V. All rights reserved.
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