Journal
CHEMICAL ENGINEERING SCIENCE
Volume 78, Issue -, Pages 186-203Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ces.2012.04.033
Keywords
Photocatalysis; Langmuir-Hinshelwood; Kinetics; Parameter estimation; Reaction engineering; Adsorption constants
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Funding
- Consejo Nacional de Ciencia y Tecnologia (CONACyT) Mexico
- Project CONACYT-Mexico-Ciencia Basica [2007-83144]
- Natural Sciences and Engineering Research Council of Canada
- [P/PIFI 2010-32MSU0017H-09]
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This study reports the kinetics of the photocatalytic degradation of phenol using four different TiO2 catalysts. It is shown that phenol yields hydroquinone, catechol, benzoquinone and acetic and formic acids as main intermediate species. A phenomenological unified kinetic model (UKM) based in a series-parallel reaction network is proposed. The UKM follows a Langmuir-Hinshelwood kinetics with this being applicable to the various TiO2 photocatalysts studied. The UKM requires a number of significant assumptions in order to be used effectively avoiding overparametization. This approach also requires that the adsorption constants be obtained independently. As a result, the UKM is adapted for each specific TiO2 photocatalyst to describe the experimental photoconversion data. It is concluded that this approach provides good and objective parameter estimates with low to moderate cross-correlation among kinetic parameters and acceptable 95% CIs. (C) 2012 Elsevier Ltd. All rights reserved.
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