Article
Engineering, Chemical
Y. Salehy, P. Clain, A. Boufares, N. Chami, J-P. Torre, D. Dalmazzone, L. Fournaison, A. Delahaye
Summary: Recent studies have explored the potential use of hydrate slurries in indirect refrigeration systems, but pipeline clogging issues due to hydrate agglomeration can arise. Additives, such as Dioctyl sodium sulfosuccinate (AOT), are commonly utilized to mitigate these problems. This study investigates the rheological properties of CO2 hydrate slurries, specifically the impact of AOT. A capillary viscometer method and a dynamic loop were employed to assess fluid behavior and collect experimental data. The study reveals a shear-thinning behavior and emphasizes the potential of AOT in significantly improving the properties of CO2 hydrate slurries.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Chemistry, Physical
Sepehr Saber, Mohammad Zargartalebi, Amin Kazemi, David Sinton
Summary: By adjusting environmental variables such as salinity and temperature, stability of Pickering phase change slurries (PPCS) can be achieved, and their shear-induced instability can be improved. Experimental results indicate that increasing salinity enhances the formulation's resistance to shear-induced instability, and within a certain volume fraction range, viscosity increases significantly. Regardless of salinity, the resulting PPCS formulations remain stable under high pressure and temperature conditions.
JOURNAL OF COLLOID AND INTERFACE SCIENCE
(2023)
Article
Chemistry, Physical
Sepehr Saber, Mohammad Zargartalebi, Vikram Soni, Hannah McPhee, Mohammad Roostaie, Alireza Darzi, Jason Riordon, Michael Holmes, Matthew Toews, David Sinton
Summary: The thermal energy recovery of a closed-loop geothermal system can be increased by using phase change slurries as working fluids. This study assessed the thermophysical properties of these slurries in the presence of common mineral contaminants and found that they can remain stable with minimal changes to their properties.
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS
(2022)
Article
Computer Science, Interdisciplinary Applications
Xiaoxing Liu, Koji Morita, Shuai Zhang
Summary: In this paper, a moving particle semi-implicit (MPS) method is developed for simulating multiphase incompressible flows with mass transfer due to vaporization. The method considers variable particle volume and introduces particle splitting technique to avoid large volume difference among particles. A source term for mass transfer rate in vaporization process is developed in the pressure Poisson equation (PPE) along with enhanced MPS schemes from previous studies.
JOURNAL OF COMPUTATIONAL PHYSICS
(2021)
Article
Energy & Fuels
Zaixing Liu, Jiguang Wang, Weiguo Liu, Yanghui Li, Chen Lang, Mengmeng Zhang, Yongchen Song
Summary: The study shows that an increase in salt concentration can significantly decrease the viscosity of hydrate slurries and improve their stability. High salinity in the aqueous phase is beneficial for extending the stable flow time of hydrate slurries.
JOURNAL OF PETROLEUM SCIENCE AND ENGINEERING
(2022)
Article
Computer Science, Interdisciplinary Applications
Everett A. Wenzel, Marco Arienti
Summary: This paper presents a method for simulating evaporation in a compressible, interface-resolved framework. The method ensures consistent mass and thermal energy transport at the phase interface, conserves mass, momentum, and energy, and can model compressible and incompressible systems. Verification and validation tests are performed, and the method is shown to be accurate and efficient in studying phase change in engineering systems.
JOURNAL OF COMPUTATIONAL PHYSICS
(2023)
Article
Energy & Fuels
Zheng Liu, Baojiang Sun, Zhiyuan Wang, Jianbo Zhang, Xuerui Wang
Summary: A model was established to predict the risk of hydrate reformation in production pipelines during offshore gas hydrate development, studying the region and higher-risk drainage pipe. A new hydrate management strategy by adding additional pumps and heaters was proposed to effectively address potential hydrate reformation risks.
Article
Mechanics
Jessica Sanchez-Vargas, Francisco J. Valdes-Parada, Mauricio A. Trujillo-Roldan, Didier Lasseux
Summary: A closed macroscopic model for quasi-steady, inertial, incompressible, two-phase generalised Newtonian flow in rigid and homogeneous porous media is derived by upscaling the pore-scale equations. The derived model includes macroscopic equations for mass and momentum balance as well as an expression for the macroscopic pressure difference between the two fluid phases. The predictions from the upscaled models are in excellent agreement with direct numerical simulations, confirming the validity of the derived macroscopic models.
JOURNAL OF FLUID MECHANICS
(2023)
Article
Engineering, Chemical
Chandan Sahu, Siddhant Kumar Prasad, Rajnish Kumar, Jitendra S. Sangwai
Summary: The rheological properties of CO2 hydrate slurries with and without the surfactant SDS were studied. It was found that dissolved CO2 actively participated in the nucleation and growth of hydrate crystals at higher pressures. The addition of SDS reduced the peak and steady-state viscosities of the slurries and exhibited pseudoplastic behavior. The presence of SDS also delayed the dissociation of CO2 hydrates and improved their stability and flowability.
SEPARATION AND PURIFICATION TECHNOLOGY
(2023)
Article
Computer Science, Interdisciplinary Applications
Pengwei Zhang, Baoguo Liu, Liming Hu, Jay N. Meegoda
Summary: A coupled multiphase flow computational model is developed to simulate gas hydrate extraction with phase transition and pore compression. The model is validated and used to investigate the factors influencing gas hydrate extraction efficiency through the simulation of a gas hydrate chimney.
COMPUTERS AND GEOTECHNICS
(2022)
Article
Thermodynamics
Kenta Inatsu, Shunsuke Abe, Tatsunori Asaoka
Summary: Sugar alcohol slurries were studied as a slurry heat medium for low/medium temperature applications, with flow characteristics investigated experimentally. Viscosity of mannitol slurry decreased with increasing solid fraction, showing pseudoplastic fluid behavior; however, no significant correlation was found between viscosity parameters and solid fraction in erythritol slurries, making power-law model inapplicable. Differences in rheological behavior between the two slurries may be due to varying flow patterns.
INTERNATIONAL JOURNAL OF REFRIGERATION
(2021)
Article
Engineering, Marine
Song Zeng, Liangjie Mao, Qingyou Liu, Guorong Wang, Juan Li
Summary: A dynamic analysis model for natural gas hydrate production riser was established, which considered the internal phase transition of hydrate multiphase flow and external marine environmental loads. The correctness of the model was verified by experiment and field testing data, showing that NGH decomposition in the middle of the riser causes a sudden pressure drop, increasing axial tension and Von Mises stress.
Article
Energy & Fuels
Shunsuke Abe, Takashi Morimoto, Tatsunori Asaoka, Hiroyuki Kumano
Summary: Sugar alcohols are utilized as heat storage materials due to their high latent heat, with their melting points ideal for recovering unused heat. In this study, the apparent specific heat of sugar alcohol slurries was investigated to estimate heat storage capabilities, with erythritol and mannitol used as the sugar alcohols. The proposed model showed good agreement between calculated values and experimental data, indicating the significant impact of freezing-point depression on the apparent specific heat of the sugar alcohol slurries.
JOURNAL OF ENERGY STORAGE
(2021)
Article
Engineering, Chemical
Xuewen Cao, Kairan Yang, Hongchao Wang, Jiang Bian
Summary: The gas-liquid flow behavior laden by hydrate particles is significant for the flow assurance of submarine natural gas hydrate production. This study developed an integrated model to investigate the gas-liquid-hydrate flow problem in a vertical pipe and analyzed the effects of particle behavior on flow pattern transition.
CHEMICAL ENGINEERING SCIENCE
(2022)
Article
Polymer Science
Christina Toigo, Milan Kracalik, Elke Bradt, Karl-Heinz Pettinger, Catia Arbizzani
Summary: The rheological properties of electrode slurries have been studied for various combinations of active materials and binders, with a shift towards water-based electrode manufacturing becoming more important. While different solvents offer benefits in terms of sustainability and safety, they also present challenges such as slurry stability issues. Li4Ti5O12 (LTO) active material shows good long-term stability and can be processed in aqueous solutions, but combining it with sodium alginate (SA) as a binder presents challenges in slurry stability. In this study, a comprehensive rheological analysis was conducted on anode slurries consisting of LTO and SA, with the use of surfactants to improve stability compared to surfactant-free slurries.
Article
Public, Environmental & Occupational Health
Steven Duret, Hong-Minh Hoang, Evelyne Derens-Bertheau, Anthony Delahaye, Onrawee Laguerre, Laurent Guillier
Article
Thermodynamics
Fabien Raoult, Stephanie Lacour, Bertrand Carissimo, Francois Trinquet, Anthony Delahaye, Laurence Fournaison
APPLIED THERMAL ENGINEERING
(2019)
Article
Thermodynamics
Ziad Youssef, Laurence Fournaison, Anthony Delahaye, Michel Pons
INTERNATIONAL JOURNAL OF REFRIGERATION-REVUE INTERNATIONALE DU FROID
(2019)
Article
Thermodynamics
P. E. Vende, F. Trinquet, S. O. L. Lacour, A. Delahaye, L. Fournaison
INTERNATIONAL JOURNAL OF THERMAL SCIENCES
(2019)
Article
Energy & Fuels
Thomas Dufour, Hong Minh Hoang, Jeremy Oignet, Veronique Osswald, Laurence Fournaison, Anthony Delahaye
Article
Thermodynamics
S. O. L. Lacour, F. Raoult, C. Tinet, L. Fournaison, A. Delahaye, F. Trinquet
EXPERIMENTAL THERMAL AND FLUID SCIENCE
(2019)
Article
Thermodynamics
R. Ben-Abdallah, D. Leducq, H. M. Hoang, L. Fournaison, O. Pateau, B. Ballot-Miguet, A. Delahaye
ENERGY CONVERSION AND MANAGEMENT
(2019)
Review
Thermodynamics
Cyrine Damak, Denis Leducq, Hong Minh Hoang, Daniele Negro, Anthony Delahaye
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Thermodynamics
Mahdjouba Akerma, Hong-Minh Hoang, Denis Leducq, Anthony Delahaye
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Thermodynamics
Steven Duret, Erwann Hamon, Hong-Minh Hoang, Valerie Stahl, Evelyne Derens-Bertheau, Anthony Delahaye, Onrawee Laguerre
INTERNATIONAL JOURNAL OF REFRIGERATION
(2020)
Article
Energy & Fuels
Fatima Doria Benmesbah, Livio Ruffine, Pascal Clain, Veronique Osswald, Olivia Fandino, Laurence Fournaison, Anthony Delahaye
Article
Food Science & Technology
Steven Duret, Hong-Minh Hoang, Laurent Guillier, Evelyne Derens-Bertheau, Claire Dargaignaratz, Stephanie Oriol, Anthony Delahaye, Onrawee Laguerre, Christophe Nguyen-the
Summary: Food refrigeration is crucial for maintaining microbiological quality but comes with high energy consumption. Increasing refrigeration temperature in the processing plant can reduce electrical power consumption, but may also lead to an increase in microbiologically defective products. Raising the cooling tunnel temperature saves more energy compared to increasing cold room temperature while achieving similar impacts on microbiology.
Article
Green & Sustainable Science & Technology
Yasmine Salehy, Anthony Delahaye, Hong Minh Hoang, Laurence Fournaison, Francois Cluzel, Yann Leroy, Bernard Yannou
Summary: This paper proposes a generic approach to assess the potential of adoption for sustainable refrigeration systems by describing their multiple performances. Through modeling and simulation of four supermarket refrigeration systems, the study shows that the electricity mix is the most influential parameter on cost and environmental impact. While CO2 refrigerant systems show promising performances, the maintenance score can be a limiting factor for their installation. The study also explores the impact of photovoltaic panels and financial support on improving cost and environmental performances.
JOURNAL OF CLEANER PRODUCTION
(2023)
Article
Engineering, Chemical
Y. Salehy, P. Clain, A. Boufares, N. Chami, J-P. Torre, D. Dalmazzone, L. Fournaison, A. Delahaye
Summary: Recent studies have explored the potential use of hydrate slurries in indirect refrigeration systems, but pipeline clogging issues due to hydrate agglomeration can arise. Additives, such as Dioctyl sodium sulfosuccinate (AOT), are commonly utilized to mitigate these problems. This study investigates the rheological properties of CO2 hydrate slurries, specifically the impact of AOT. A capillary viscometer method and a dynamic loop were employed to assess fluid behavior and collect experimental data. The study reveals a shear-thinning behavior and emphasizes the potential of AOT in significantly improving the properties of CO2 hydrate slurries.
CHEMICAL ENGINEERING SCIENCE
(2023)
Article
Thermodynamics
Walid Samah, Pascal Clain, Francois Rioual, Laurence Fournaison, Anthony Delahaye
Summary: This study focuses on the growth, adhesion, and detachment phenomena of ice by liquid jets on different types of surfaces. The results show that ice adheres less to superhydrophobic surfaces and hydrophobic surfaces detach the ice layer faster compared to untreated surfaces.
APPLIED THERMAL ENGINEERING
(2024)
Article
Engineering, Chemical
Qing Han, Mengqing Shi, Linkai Han, Di Liu, Mingwei Tong, Yuxin Xie, Zhonghua Xiang
Summary: Developing highly efficient bifunctional oxygen electrocatalysts is crucial for zinc-air flow batteries. Metal-organic frameworks (MOFs) and covalent organic polymers (COPs) have emerged as promising alternatives due to their designable and controllable atomic-level structures. However, their catalytic performances are limited by conductivity and catalytic activity. In this study, nanosheet FeNi-MOF and iron phthalocyanine rich COP hybrid materials are assembled through the pi-pi stacking effect to create highly efficient bifunctional electrocatalysts. The resulting catalyst exhibits superior catalytic performance and stability, making it a promising candidate for zinc-air flow batteries.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Daria Grigorash, Dmytro Mihrin, Rene Wugt Larsen, Erling H. Stenby, Wei Yan
Summary: The article introduces a new approach to describe the cross-association between molecules, allowing for the simulation of weakly bound molecular complexes with different conformations in mixtures. By incorporating this approach into the equation of state, accurate predictions of vapor-liquid equilibrium and liquid-liquid equilibrium can be made. The new method is validated through experiments on alcohol and acid mixtures, with the results compared to experimental data, demonstrating its accuracy and reliability.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Mohammed Al-Sharabi, Daniel Markl, Vincenzino Vivacqua, Prince Bawuah, Natalie Maclean, Andrew P. E. York, Axel Zeitler
Summary: This study used terahertz pulsed imaging to investigate the transport process of different solvents into ceramic catalytic materials. The results showed that the heating rate of the samples influenced the water transport rate, while the viscosity of 1-octanol slowed down its transport.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chukwunonso Anyaoku, Sati Bhattacharya, Rajarathinam Parthasarathy
Summary: This study aimed to enhance understanding of settling dynamics in viscoelastic fluids by developing a semi-empirical correlation and a dimensionless ratio, which accurately described the characteristics of settling suspensions.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Antti I. Koponen, Janika Viitala, Atsushi Tanaka, Baranivignesh Prakash, Olli-Ville Laukkanen, Ari Jasberg
Summary: This study focuses on the development of foam application chemicals for the paper and board industry. The research explores the rheology of the polyvinyl alcohol foam used in the process. Measurements were conducted to determine the foam viscosity and slip flow. The results suggest that slip flow contributes significantly to the total flow rate, and the obtained viscosity and slip models provide a solid foundation for industrial processes.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Dalei Sun, Jinghui Cai, Yating Yang, Zhiwu Liang
Summary: In this study, Fe-doped alpha-Bi2O3 catalysts with different Fe/Bi molar ratios were synthesized and utilized in the carbonylation of isobutyl amine with CO2. The results showed that Fe doping significantly enhanced the catalytic abilities of alpha-Bi2O3.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Yuan Tian, Xinxin Wang, Yanrong Liu, Wenping Hu
Summary: This paper predicts the solubility of nitrogen gas in ionic liquids (ILs) using two quantitative structure-property relationship (QSPR) models. By combining machine learning methods and ionic fragments contribution method, the accuracy and reliability of the prediction models are improved.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Liwang Wang, Wei Liu, Pan Yang, Yulong Chang, Xiaoxu Duan, Lingyu Xiao, Yaoming Hu, Jiwei Wu, Liang Ma, Hualin Wang
Summary: This study investigates the effective phase interfacial area (ae) of hydro-jet cyclones at different injection angles. The results show that a 45 degrees upward incidence angle yields the most favorable flow field characteristics for efficient mass transfer. The significant enhancement in ae of the hydro-jet cyclones offers the advantage of reducing equipment volume and cost savings.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Chuanjun Wu, Jiangzhi Chen, Jiyue Sun, I-Ming Chou, Shenghua Mei, Juezhi Lin, Lei Jiang
Summary: In this study, the solubility of H2S hydrate in water was measured using Raman spectroscopy. The results showed that the solubility increases with temperature under certain equilibrium conditions, and the solubility also depends on pressure and temperature under different equilibrium conditions. A thermodynamic model based on the van der Waals-Platteeuw theory was developed to predict the solubility, demonstrating its accuracy.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Lorenzo Brivio, Serena Meini, Mattia Sponchioni, Davide Moscatelli
Summary: This study investigates the influence of three main parameters and proposes a kinetic model to predict the optimal operating conditions for high yield of dimethyl terephthalate (DMT) in the chemical recycling process of polyethylene terephthalate (PET).
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Hongju Lin, Fanhui Liao, Yanchang Chu, Mingyu Xie, Lun Pan, Yuanyuan Wang, Lijian Leng, Donghai Xu, Le Yang, Gangfeng Ouyang
Summary: A honeycomb NiCo/C-Na catalyst with a micro-meso-macroporous structure has been fabricated and shown to have significantly higher catalytic activity for the decarboxylation of fatty acids. It also proves to be efficient in upgrading sludge HTL bio-crude, resulting in a biofuel with decreased viscosity and increased density.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Xiaoxian Li, Rui Li, Min Lin, Mingde Yang, Yulong Wu
Summary: A series of coated non-noble metal porous carbon catalysts were synthesized and applied to the aqueous-phase deoxygenation of algal bio-oil. One of the catalysts showed excellent deoxygenation selectivity and catalytic activity at 250 degrees C. The catalyst exhibited good hydrothermal stability and the reaction mechanism was proposed based on product analysis and active site analysis.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
M. V. Chudakova, M. V. Popov, P. A. Korovchenko, E. O. Pentsak, A. R. Latypova, P. B. Kurmashov, A. A. Pimenov, E. A. Tsilimbaeva, I. S. Levin, A. G. Bannov, A. V. Kleymenov
Summary: A series of catalysts with different potassium contents were prepared using solution combustion synthesis and characterized using various techniques. The results showed that the potassium content affected the phase composition and texture of the catalysts. The addition of a small amount of potassium resulted in a change in particle size distribution, leading to higher hydrogen yield. The Ni-1%K2O/Al2O3 catalyst exhibited the highest hydrogen yield at temperatures of 675 and 750 degrees Celsius.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Aliakbar Roosta, Nima Rezaei
Summary: In this study, we modified the electrolyte cubic plus association equation of state (e-CPA EoS) and integrated it with two electrical conductivity models to estimate the electrical conductivity of 11 monovalent electrolyte solutions in water. The modified e-CPA model demonstrated better performance and the hybridization with electrical conductivity models resulted in two predictive models for estimating the electrical conduction of dilute and concentrated electrolyte solutions. These predictive models showed relative average percentage deviations (AARD) of 11.15% and 13.87% over wide ranges of temperature and electrolyte concentration.
CHEMICAL ENGINEERING SCIENCE
(2024)
Article
Engineering, Chemical
Haoren Niu, Jianzheng Wang, Qingzhu Jia, Qiang Wang, Jin Zhao, Fangyou Yan
Summary: A study developed two quantitative structure-property relationship models for the complexation performance of alpha- and beta-cyclodextrins and validated their stability and predictive ability through internal and external validation. The models showed robustness and satisfactory performance, as demonstrated by the experimental results and model validations. These models can effectively predict the binding constants between cyclodextrins and various types of molecules, providing valuable tools for cyclodextrin design.
CHEMICAL ENGINEERING SCIENCE
(2024)