Journal
CHEMICAL ENGINEERING JOURNAL
Volume 243, Issue -, Pages 234-243Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2013.12.099
Keywords
Dilute sulfuric acid pretreatment; Cashew apple bagasse; Kluyveromyces marxianus; Saccharomyces cerevisiae; Ethanol; Xylitol
Categories
Funding
- CAPES (from Brazil)
- CNPq (from Brazil)
- FUNCAP (from Brazil)
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Pretreatment conditions such as the concentration of sulfuric acid added, solid concentration and the contact time were studied to maximize the yields from the bagasse. The best condition for dilute acid pretreatment was obtained when using 0.6 mol/L H2SO4 for 15 min at 121 degrees C. At this pretreatment condition, no detectable quantities of furfural or hydroxymethyl furfural were observed in the hydrolyzate fraction after treatment with Ca(OH)(2). Scanning electron microscopy imaging showed the physical structural changes of cashew apple bagasse when it was pretreated with dilute sulfuric acid. Dilute-sulfuric acid pretreatment of CAB released hemicellulose-derived sugars to the liquid and these carbohydrates can be used to ethanol and xylitol production. An ethanol concentration of 10.0 g/L was obtained after 4 h of fermentation by Saccharomyces cerevisiae in agitated Flasks, with a yield of 0.49 g/g(glucose) and a productivity of 1.43 g/(L h) In a 41 bench-scale bioreactor using S. cerevisiae, the maximum ethanol concentration obtained was 9.59 +/- 1.74 g/L, and the maximum productivity obtained was 1.22 +/- 0.06 g/(L h) Kluyveromyces marxianus CCA 510 produced ethanol and xylitol, reaching a concentration of 11.89 +/- 0.34 g/L and 6.76 +/- 0.28 g/L, respectively, at 96 h. (C) 2014 Elsevier B.V. All rights reserved.
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