4.7 Article

Triphos-Fe dinitrogen and dinitrogen-hydride complexes: relevance to catalytic N-2 reductions

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 84, Pages 11953-11956

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc07466f

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Funding

  1. CNRS
  2. Universite de Toulouse

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The two electron reduction of iron complexes [((PP2Cy)-P-R)Fe(Cl)(2)] (R = Ph or tBu) 2a-b afforded complexes [((PP2Cy)-P-R)Fe(N-2)(2)] 4a-b. Protonation of 4a at the metal center and subsequent reduction to Fe(i)-H species lead to complex [((PP2Cy)-P-Ph)Fe(N-2)(H)(2)] 6avia a spontaneous disproportionation reaction. Complex 4a behaves as one of the most efficient monometallic Fe-catalysts reported to date for N-2-to-N(SiMe3)(3) functionalization under atmospheric pressure.

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