4.7 Article

Spiral Eu(iii) coordination polymers with circularly polarized luminescence

Journal

CHEMICAL COMMUNICATIONS
Volume 54, Issue 76, Pages 10695-10697

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c8cc05147j

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Funding

  1. JSPS KAKENHI [JP18H04497]
  2. [18H02041]
  3. [18H04496]
  4. [JP17H06375]

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A spiral-type chiral Eu(iii) coordination polymer showed strong luminescence (emission quantum yield phi(f-f) = 57% and photosensitized energy transfer efficiency (sens) = 53%) and effective CD and CPL properties (g(CPL) = 0.17) when compared with a mono-nuclear chiral Eu(iii) complex in the solid state (phi(f-f) = 36%, (sens) = 14%, and g(CPL) = 0.09).

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