The open d-shell enforces the active space in 3d metal catalysis: highly enantioselective chromium(ii) pincer catalysed hydrosilylation of ketones

One-Pot Sequential Kinetic Profiling of a Highly Reactive Manganese Catalyst for Ketone Hydroboration: Leveraging σ-Bond Metathesis via Alkoxide Exchange Steps

(2018) Vladislav Vasilenko et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination Chemistry of the PdmBOX Pincer Ligand: Reactivity at the Metal and the Ligand

(2017) Jan Wenz et al.   EUROPEAN JOURNAL OF INORGANIC CHEMISTRY

A Readily Accessible Chiral NNN Pincer Ligand with a Pyrrole Backbone and Its Ni(II) Chemistry: Syntheses, Structural Chemistry, and Bond Activations

(2017) Jan Wenz et al.   INORGANIC CHEMISTRY

Radical Changes in Lewis Acid Catalysis: Matching Metal and Substrate

(2016) Tim Bleith et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic C–F bond activation of geminal difluorocyclopropanes by nickel(i) complexes via a radical mechanism

(2016) Jan Wenz et al.   CHEMICAL COMMUNICATIONS

Activation of Aryl Halides by Nickel(I) Pincer Complexes: Reaction Pathways of Stoichiometric and Catalytic Dehalogenations

(2016) Christoph A. Rettenmeier et al.   INORGANIC CHEMISTRY

Mechanism of the Iron(II)-Catalyzed Hydrosilylation of Ketones: Activation of Iron Carboxylate Precatalysts and Reaction Pathways of the Active Catalyst

(2016) Tim Bleith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Improving 1-Hexene Incorporation of Highly Active Cp–Chromium-Based Ethylene Polymerization Catalysts

(2016) Mathias Ronellenfitsch et al.   MACROMOLECULES

Chromium(II) Pincer Complexes with Dearomatized PNP and PNC Ligands: A Comparative Study of Their Catalytic Ethylene Oligomerization Activity

(2016) Thomas Simler et al.   ORGANOMETALLICS

Recent Advances in the Asymmetric Nozaki–Hiyama–Kishi Reaction

(2016) Guozhu Zhang et al.   SYNTHESIS-STUTTGART

Iron Achieves Noble Metal Reactivity and Selectivity: Highly Reactive and Enantioselective Iron Complexes as Catalysts in the Hydrosilylation of Ketones

(2015) Tim Bleith et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Regio- and Chemoselective Kumada–Tamao–Corriu Reaction of Aryl Alkyl Ethers Catalyzed by Chromium Under Mild Conditions

(2015) Xuefeng Cong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Coordination polymers and molecular structures among complexes of mercury(II) halides with selected 1-benzoylthioureas

(2015) Andrzej Okuniewski et al.   POLYHEDRON

Stereoselective Hydrodehalogenation via a Radical-Based Mechanism Involving T-Shaped Chiral Nickel(I) Pincer Complexes

(2014) Christoph Rettenmeier et al.   CHEMISTRY-A EUROPEAN JOURNAL

Chemoselective Chromium(II)-Catalyzed Cross-Coupling Reactions of Dichlorinated Heteroaromatics with Functionalized Aryl Grignard Reagents

(2014) Andreas K. Steib et al.   CHEMISTRY-A EUROPEAN JOURNAL

Room-Temperature Chromium(II)-Catalyzed Direct Arylation of Pyridines, Aryl Oxazolines, and Imines Using Arylmagnesium Reagents

(2014) Olesya M. Kuzmina et al.   ORGANIC LETTERS

Reactivity with Alkylaluminum of a Chromium Complex of a Pyridine-Containing PNP Ligand: Redox N–P Bond Cleavage

(2014) Ahmed Alzamly et al.   ORGANOMETALLICS

Copper-Boxmi Complexes as Highly Enantioselective Catalysts for Electrophilic Trifluoromethylthiolations

(2013) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Enantioselective Iron-Catalyzed Azidation of β-Keto Esters and Oxindoles

(2013) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Efficient Chromium(II)-Catalyzed Cross-Coupling Reactions between Csp2 Centers

(2013) Andreas K. Steib et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

‘One-pot’ Hammett plots: a general method for the rapid acquisition of relative rate data

(2012) Hon Man Yau et al.   CHEMICAL COMMUNICATIONS

Highly Enantioselective Copper-Catalyzed Alkylation of β-Ketoesters and Subsequent Cyclization to Spirolactones/Bi-spirolactones

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Highly Enantioselective Copper-Catalyzed Electrophilic Trifluoromethylation of β-Ketoesters

(2012) Qing-Hai Deng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Aminophosphine-Based Chromium Catalysts for Selective Ethylene Tetramerization

(2012) Yacoob Shaikh et al.   ORGANOMETALLICS

The Synthesis of a New Class of Chiral Pincer Ligands and Their Applications in Enantioselective Catalytic Fluorinations and the Nozaki-Hiyama-Kishi Reaction

(2011) Qing-Hai Deng et al.   CHEMISTRY-A EUROPEAN JOURNAL

Trianionic NCN3–Pincer Complexes of Chromium in Four Oxidation States (CrII, CrIII, CrIV, CrV): Determination of the Active Catalyst in Selective 1-Alkene to 2-Alkene Isomerization

(2011) Kevin P. McGowan et al.   ORGANOMETALLICS

Selective ethylene oligomerization: Recent advances in chromium catalysis and mechanistic investigations

(2010) Theodor Agapie   COORDINATION CHEMISTRY REVIEWS

Chiral Bis(pyridylimino)isoindoles: A Highly Modular Class of Pincer Ligands for Enantioselective Catalysis

(2008) Björn K. Langlotz et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION