Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 15, Pages 1894-1896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc48489k
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Funding
- Italian Ministry of University and Scientific Research (PRIN KAWXCL)
- French Ministry of Foreign Affairs
- NSERC
- AITF
- Micralyne, Inc.
- Killam Trust
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UV-visible absorption spectroelectrochemistry elucidated the different redox behaviours of Fe-III- and Co-III-mimochrome VI artificial enzymes, adsorbed on mesoporous conductive films of ITO. The reduction of the ferric complex was rapid and reversible, while the cobaltic complex exhibited irreversible processes probably related to multiple coordination states.
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