4.7 Article

Lewis base-catalyzed reactions of cyclopropenones: novel synthesis of mono-or multi-substituted allenic esters

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 1, Pages 115-117

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46470a

Keywords

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Funding

  1. Shanghai Municipal Committee of Science and Technology [11JC1402600]
  2. National Basic Research Program of China [(973)- 2009CB825300]
  3. National Natural Science Foundation of China [21072206, 20472096, 21102166, 21372241, 21302203, 21372250, 20672127, 21121062, 20732008]

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The reactions of cyclopropenones with nucleophiles (H2O ormethanol) could be catalyzed by nitrogen-containing Lewis bases or phosphoruscontaining Lewis bases, affording the corresponding mono-or multisubstituted allenic esters in moderate to excellent yields.

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