Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 72, Pages 10406-10408Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc04183f
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A simple Pd/SiO2 catalyst which was modified with the ionic liquid [BMPL][DCA] gave an excellent yield of 88% towards cis-2-hexene in the stereoselective hydrogenation of 2-hexyne. The catalyst outperforms, even at full conversion, the commonly used lead-poisoned, toxic Lindlar catalyst and supported colloidal-based Pd as well.
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