4.7 Article

Photoresponsive liquid crystals based on halogen bonding of azopyridines

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 68, Pages 9647-9649

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc02344g

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Funding

  1. Major Project of International Cooperation of the Ministry of Science and Technology [2013DFB50340]
  2. Major Project of Beijing Science and Technology Program [Z121100006512002]
  3. National Natural Science Fund [E030701]
  4. National Natural Science Foundation of China [51322301]
  5. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry

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A series of photoresponsive halogen-bonded liquid crystals (LCs) were successfully constructed using molecular halogen and azopyridine compounds, which show interesting properties of photoinduced phase transition upon UV irradiation. In addition, bromine-bonded LCs were first obtained with high mesophase stability.

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