Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 91, Pages 14153-14156Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc05511j
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Funding
- Natural Science Foundation of China [21373040, 21120102036, 21361130020, 91233201]
- Basic Research Program of China [2014CB239402]
- PhD Program Foundation of Ministry of Education of China [20130041110024]
- Swedish Research Council
- Swedish Energy Agency
- K & A Wallenberg Foundation
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A series of nickel complexes containing N-5-pentadentate ligands with different amine-to-pyridine ratios were studied for electrochemical H-2 production in neutral water and the one with a diamine-tripyridine ligand displays a TON of up to 308000 over 60 h electrolysis at -1.25 V vs. SHE, with a Faradaic efficiency of similar to 91%.
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