Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 87, Pages 13391-13393Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/C4CC06111J
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Funding
- Nanyang Technological University [R06113]
- Ministry of Education, Singapore [M0E2013-T3-1-004]
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A novel and efficient dual catalysis approach by concurrent activation of glycals and (o-azaaryl)-carboxaldehydes using palladium and N-heterocyclic carbene has been developed. The two electrophiles could react after activation through formation of the Breslow intermediate and a pi-allyl Pd complex, widening the scope of reacting glycosylation partners and opening up possibilities for future glycosylation.
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