Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 7, Pages 836-838Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc47001f
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Funding
- NSF CCI grant through the Center for Sustainable Materials Chemistry [CHE-1102637]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1102637] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1152250] Funding Source: National Science Foundation
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A new tellurium-substituted Lindqvist-type polyoxoniobate [H2TeNb5O19](5-) was synthesized as a tetramethylammonium salt. When irradiated with a Xe lamp, a water-methanol solution of this cluster showed exceptionally high H-2-evolution activity suggesting cocatalysis by the hexaniobate cluster and metallic tellurium, both of which are formed as photodecomposition products.
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