Copper-mediated aromatic amination reaction and its application to the total synthesis of natural products

A Concise and Versatile Synthesis of Alkaloids fromKopsia tenuis: Total Synthesis of (±)-Lundurine A and B

(2014) Shigeru Arai et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Cu(II)-Mediated C–H Amidation and Amination of Arenes: Exceptional Compatibility with Heterocycles

(2014) Ming Shang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Total Synthesis of (±)-Lundurine B

(2014) Masaki Hoshi et al.   ORGANIC LETTERS

Copper-Catalyzed Carboxamide-Directed Ortho Amination of Anilines with Alkylamines at Room Temperature

(2014) Qiong Li et al.   ORGANIC LETTERS

AN INTRAMOLECULAR AMINATION OF ARYL HALIDES WITH A COMBINATION OF COPPER (I) IODIDE AND CESIUM ACETATE: PREPARATION OF 5,6-DIMETHOXYINDOLE-1,2-DICARBOXYLIC ACID 1-BENZYL ESTER 2-METHYL ESTER

(2014)   ORGANIC SYNTHESES

Directed Amination of Non-Acidic Arene CH Bonds by a Copper-Silver Catalytic System

(2013) Ly Dieu Tran et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Protecting-Group-Free Total Synthesis of (−)-Rhazinilam and (−)-Rhazinicine using a Gold-Catalyzed Cascade Cyclization

(2013) Kenji Sugimoto et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Total synthesis of PDE-I and -II by copper-mediated double aryl amination

(2013) Kentaro Okano et al.   TETRAHEDRON

Synthetic Studies on Natural Products with Aromatic Nitrogen Heterocycles Based on Development of the Methods for the Formation of Aryl Carbon-Nitrogen Bond

(2013) Kentaro Okano   YAKUGAKU ZASSHI-JOURNAL OF THE PHARMACEUTICAL SOCIETY OF JAPAN

Arynes and Cyclohexyne in Natural Product Synthesis

(2012) Christian M. Gampe et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Copper-catalyzed intramolecular direct amination of sp2 C–H bonds for the synthesis of N-aryl acridones

(2012) Wang Zhou et al.   CHEMICAL COMMUNICATIONS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

The Complementary Competitors: Palladium and Copper in C–N Cross-Coupling Reactions

(2012) Irina P. Beletskaya et al.   ORGANOMETALLICS

Photoinduced Ullmann C-N Coupling: Demonstrating the Viability of a Radical Pathway

(2012) S. E. Creutz et al.   SCIENCE

Copper-Catalyzed Amidation of 2-Phenylpyridine with Oxygen as the Terminal Oxidant

(2011) Alex John et al.   JOURNAL OF ORGANIC CHEMISTRY

Palladium-Catalyzed Intermolecular Directed C−H Amidation of Aromatic Ketones

(2011) Bin Xiao et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intramolecular Oxidative C−N Bond Formation for the Synthesis of Carbazoles: Comparison of Reactivity between the Copper-Catalyzed and Metal-Free Conditions

(2011) Seung Hwan Cho et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed C−H Aminations of Anilides withN-Fluorobenzenesulfonimide

(2011) Kai Sun et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecular C–H Amination with Alkylamines

(2011) Eun Jeong Yoo et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed Highly Regioselective Oxidative CH Bond Amidation of 2-Arylpyridine Derivatives and 1-Methylindoles

(2010) Qi Shuai et al.   ADVANCED SYNTHESIS & CATALYSIS

Synthetic Methods for the Generation and Preparative Application of Benzyne

(2010) Tsugio Kitamura   AUSTRALIAN JOURNAL OF CHEMISTRY

Total synthesis of PDE-II by copper-mediated double amination

(2010) Kentaro Okano et al.   CHEMICAL COMMUNICATIONS

Synthesis of Primary Aryl Amines Through a Copper-Assisted Aromatic Substitution Reaction with Sodium Azide

(2010) John T. Markiewicz et al.   JOURNAL OF ORGANIC CHEMISTRY

Total Syntheses of Nitrogen-Containing Cyclic Natural Products Based on Aryl Amination

(2010) Kentaro Okano et al.   JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN

A Direct Intramolecular C−H Amination Reaction Cocatalyzed by Copper(II) and Iron(III) as Part of an Efficient Route for the Synthesis of Pyrido[1,2-a]benzimidazoles fromN-Aryl-2-aminopyridines

(2010) Honggen Wang et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Pd-Catalyzed Intermolecularortho-C−H Amidation of Anilides byN-Nosyloxycarbamate

(2010) Ka-Ho Ng et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Palladium-Catalyzed Amination of Aromatic C−H Bonds with Oxime Esters

(2010) Yichen Tan et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Copper-Catalyzed IntramolecularN-Arylation of Quinazolinones: Facile Convergent Approach to (−)-Circumdatins H and J

(2010) Umesh A. Kshirsagar et al.   ORGANIC LETTERS

Direct observation of CuI/CuIII redox steps relevant to Ullmann-type coupling reactions

(2010) Alicia Casitas et al.   Chemical Science

Palladium-Catalyzed Amidation of Unactivated C(sp3)H Bonds: from Anilines to Indolines

(2009) Julia J. Neumann et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Catalytic CC, CN, and CO Ullmann-Type Coupling Reactions

(2009) Florian Monnier et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

A General Route to Cyclopeptide Alkaloids: Total Syntheses and Biological Evaluation of Paliurines E and F, Ziziphines N and Q, Abyssenine A, Mucronine E, and Analogues

(2009) Mathieu Toumi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pd(II)-Catalyzed Amination of C−H Bonds Using Single-Electron or Two-electron Oxidants

(2009) Tian-Sheng Mei et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Evolution of a Fourth Generation Catalyst for the Amination and Thioetherification of Aryl Halides

(2008) John F. Hartwig   ACCOUNTS OF CHEMICAL RESEARCH

Copper/Amino Acid Catalyzed Cross-Couplings of Aryl and Vinyl Halides with Nucleophiles†

(2008) Dawei Ma et al.   ACCOUNTS OF CHEMICAL RESEARCH

CH Functionalization/CN Bond Formation: Copper-Catalyzed Synthesis of Benzimidazoles from Amidines

(2008) Gordon Brasche et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Anion–arene adducts: C–H hydrogen bonding, anion–π interaction, and carbon bonding motifs

(2008) Benjamin P. Hay et al.   CHEMICAL COMMUNICATIONS

Copper-Mediated Coupling Reactions and Their Applications in Natural Products and Designed Biomolecules Synthesis

(2008) Gwilherm Evano et al.   CHEMICAL REVIEWS

Synthesis of β-, γ-, and δ-Lactams via Pd(II)-Catalyzed C−H Activation Reactions

(2008) Masayuki Wasa et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Orthogonal Pd- and Cu-Based Catalyst Systems for C- and N-Arylation of Oxindoles

(2008) Ryan A. Altman et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Oxidative Pd(II)-Catalyzed C−H Bond Amination to Carbazole at Ambient Temperature

(2008) James A. Jordan-Hore et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A mild inter- and intramolecular amination of aryl halides with a combination of CuI and CsOAc

(2008) Tetsuji Kubo et al.   TETRAHEDRON

Total Synthesis of (+)-Yatakemycin

(2007) Kentaro Okano et al.   Chemistry-An Asian Journal

First Total Synthesis of Trimeric Indole Alkaloid, Psychotrimine

(2007) Yohei Matsuda et al.   ORGANIC LETTERS