4.7 Article

A plutonium-based single-molecule magnet

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 60, Pages 8171-8173

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03400g

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The magnetic properties of the 5f5 [tris-(tri-1-pyrazolylborato)-plutonium(III)] complex have been investigated by ac susceptibility measurements, showing it to be the first plutonium single-molecule magnet; its magnetic relaxation slows down with decreasing temperature through a thermally activated mechanism followed by a quantum tunnelling regime below 5 K.

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