Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 62, Pages 8575-8577Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03779k
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A new polyoxomolybdate-based hybrid platform TBA(4)[PMo11O39-{Sn(p-C6H4I)}] is reported. The presence of a post-functionalisable iodo-aryl moiety allows the grafting of a ferrocenyl moiety onto the POM. The electrochemical characterisation shows the effect of molybdenum on the electron reservoir properties of POM-based hybrids, which are further enhanced upon the addition of an acid.
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