4.7 Article

Exploring structural trends for complexes of Me2E(OSO2CF3)(2) (E = Si, Ge, Sn) with pyridine derivatives

Journal

CHEMICAL COMMUNICATIONS
Volume 50, Issue 59, Pages 7979-7981

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc01109k

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Funding

  1. Natural Sciences and Engineering Council of Canada (NSERC)

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The coordination of Me2E(OTf)(2) (E = Si, Ge, Sn) acceptors by dmap or 2,2'- bipy furnishes two series of complexes which exhibit distinct structural trends that correlate with the covalent radii of the tetrael elements, and which contrast complexes of these ligands with EX4 (X = Cl or Br).

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