Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 58, Pages 7893-7896Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4cc03266g
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Funding
- JSPS [23550116]
- MEXT [24105506]
- Grants-in-Aid for Scientific Research [23550116, 26105710, 24105506] Funding Source: KAKEN
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Kinetic resolution of racemic planar-chiral metallocenes was performed through the conjugate addition of a nucleophile to the enal part of substrates. While no enantiomeric discrimination was found with low-molecular-weight organocatalysts, a properly designed resin-supported peptide catalyzed the reaction in a highly selective manner.
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