Journal
CHEMICAL COMMUNICATIONS
Volume 50, Issue 75, Pages 11056-11059Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc46851h
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Funding
- National Natural Science Foundation of China [21272255, 21121062]
- Science and Technology Commission of Shanghai Municipality [13QA1404200, 13JC1406900]
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Iridium complexes of novel NCP pincer ligands containing pyridine and phosphinite arms have been synthesized. One Ir complex shows good catalytic activity for alkane dehydrogenation, and all complexes are highly active for olefin isomerization. A combination of the Ir complex and a (PNN)Fe pincer complex catalyzes the formation of linear alkylboronates selectively from internal olefins via sequential olefin isomerization-hydroboration.
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