4.7 Article

Abrupt spin crossover in an iron(III) quinolylsalicylaldimine complex: structural insights and solvent effects

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 56, Pages 6340-6342

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42125b

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Funding

  1. National Science and Technology Development Agency [P-10-11181]
  2. Australian Research Council
  3. Development and Promotion of Science and Technology Talents Project

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The first Fe(III) qsal-X complex exhibiting abrupt complete spin crossover at 228 K with a hysteresis of 8 K, [Fe(qsal-I)(2)]OTf is reported. Structural studies of the MeOH solvate in the LS and HS state and at the spin transition are described.

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