Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 87, Pages 10236-10238Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45911j
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A regioselective Heck reaction of aliphatic olefins and aryl bromides is realized at internal carbons of olefins. Methanol solvent promoted halide ionization from neutral arylpalladium halide complexes via hydrogen bonding, so as to create cationic aryl-Pd species for regioselective olefin insertion.
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