Metal-free carbonitration of alkenes using K2S2O8

Transition-metal-free Oxidative Coupling Reactions for the Formation of C–C and C–N Bonds Mediated by TEMPO and its Derivatives

(2014) Sandip Murarka et al.   CHIMIA

Silver-Catalyzed Decarboxylative Acylarylation of Acrylamides with α-Oxocarboxylic Acids in Aqueous Media

(2013) Hua Wang et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free Radical Azidoarylation of Alkenes: Rapid Access to Oxindoles by Cascade CN and CC Bond-Forming Reactions

(2013) Kiran Matcha et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of Oxindoles by Iron-Catalyzed Oxidative 1,2-Alkylarylation of Activated Alkenes with an Aryl C(sp2)H Bond and a C(sp3)H Bond Adjacent to a Heteroatom

(2013) Wen-Ting Wei et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Direct Annulations toward Phosphorylated Oxindoles: Silver-Catalyzed Carbon-Phosphorus Functionalization of Alkenes

(2013) Ya-Min Li et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Aerobic Oxysulfonylation of Alkenes Leading to Secondary and Tertiary β-Hydroxysulfones

(2013) Qingquan Lu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Simple alcohols promoted direct C–H arylation of unactivated arenes with aryl halides

(2013) Wei Liu et al.   CHEMICAL COMMUNICATIONS

Metal-free oxidative hydroxyalkylarylation of activated alkenes by direct sp3 C–H functionalization of alcohols

(2013) Yuan Meng et al.   CHEMICAL COMMUNICATIONS

Synthesis of β-Nitroamines via Classical Mannich and Aza-Henry Reactions

(2013) Mardia El-Sayed et al.   CURRENT ORGANIC CHEMISTRY

Synthesis of Sulfonated Oxindoles by Potassium Iodide Catalyzed Arylsulfonylation of Activated Alkenes with Sulfonylhydrazides in Water

(2013) Xiaoqing Li et al.   JOURNAL OF ORGANIC CHEMISTRY

Multifold Bond Cleavage and Formation between MeOH and Quinoxalines (or Benzothiazoles): Synthesis of Carbaldehyde Dimethyl Acetals

(2013) Yunkui Liu et al.   JOURNAL OF ORGANIC CHEMISTRY

Stereoselective Nitration of Olefins with tBuONO and TEMPO: Direct Access to Nitroolefins under Metal-free Conditions

(2013) Soham Maity et al.   ORGANIC LETTERS

Metal-free oxidative tandem coupling of activated alkenes with carbonyl C(sp2)–H bonds and aryl C(sp2)–H bonds using TBHP

(2013) Ming-Bo Zhou et al.   Chemical Science

Recent advances in transition-metal-free direct C–C and C–heteroatom bond forming reactions

(2013) Vaibhav P. Mehta et al.   RSC Advances

Highly Stereoselective Metal-Free Oxyaminations Using Chiral Hypervalent Iodine Reagents

(2012) Umar Farid et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Synthesis of 3-Fluoro-3-aryl Oxindoles: Direct Enantioselective α Arylation of Amides

(2012) Linglin Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

(2012) Hongli Liu et al.   CHEMICAL COMMUNICATIONS

Recent advances in transition-metal-free carbon–carbon and carbon–heteroatom bond-forming reactions using arynes

(2012) Anup Bhunia et al.   CHEMICAL SOCIETY REVIEWS

Metal-Free Synthesis of 3,3-Disubstituted Oxoindoles by Iodine(III)-Catalyzed Bromocarbocyclizations

(2012) David C. Fabry et al.   CHEMISTRY-A EUROPEAN JOURNAL

Approach to Polysubstituted 4-Pyridones from N-Aryl Acetoacetamides via a N to C 1,3-Acyl Migration Mediated by Sodium Persulfate

(2012) Zhiguo Zhang et al.   JOURNAL OF ORGANIC CHEMISTRY

Benzylation of Nitroalkanes Using Copper-Catalyzed Thermal Redox Catalysis: Toward the Facile C-Alkylation of Nitroalkanes

(2012) Peter G. Gildner et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Direct arylation of phenanthroline derivatives via oxidative C–H/C–H cross-coupling: synthesis and discovery of excellent ligands

(2012) Bijin Li et al.   ORGANIC & BIOMOLECULAR CHEMISTRY

Transition-Metal-Free Synthesis of Oxindoles by Potassium tert-Butoxide-Promoted Intramolecular α-Arylation

(2012) Astrid Beyer et al.   ORGANIC LETTERS

Intramolecular Dehydrogenative Coupling of sp2 C–H and sp3 C–H Bonds: An Expeditious Route to 2-Oxindoles

(2012) Santanu Ghosh et al.   ORGANIC LETTERS

Organocatalyzed arylalkylation of activated alkenes via decarboxylation of PhI(O2CR)2: efficient synthesis of oxindoles

(2012) Tao Wu et al.   TETRAHEDRON

A Facile Pathway to Enantiomerically Enriched 3-Hydroxy-2-Oxindoles: Asymmetric Intramolecular Arylation of α-Keto Amides Catalyzed by a Palladium-DifluorPhos Complex

(2011) Liang Yin et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Enantioselective Metal-Free Diamination of Styrenes

(2011) Caren Röben et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Palladium-Catalyzed Oxidative Arylalkylation of Activated Alkenes: Dual CH Bond Cleavage of an Arene and Acetonitrile

(2011) Tao Wu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Addition of halide to π-bond directly from aqueous NaX solution: a general strategy for installation of two different functional groups

(2011) Palash Pandit et al.   CHEMICAL COMMUNICATIONS

Palladium(II)-Catalyzed Alkene Functionalization via Nucleopalladation: Stereochemical Pathways and Enantioselective Catalytic Applications

(2011) Richard I. McDonald et al.   CHEMICAL REVIEWS

Palladium-Catalyzed Oxidative Aryltrifluoromethylation of Activated Alkenes at Room Temperature

(2011) Xin Mu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Base-Mediated Intermolecular sp2C−H Bond Arylation via Benzyne Intermediates

(2011) Thanh Truong et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Intermolecular Oxidative C–N Bond Formation under Metal-Free Conditions: Control of Chemoselectivity between Aryl sp2and Benzylic sp3C–H Bond Imidation

(2011) Hyun Jin Kim et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Oxyaminations of Alkenes Using Hydroxamic Acids

(2011) Valerie A. Schmidt et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

A Metal-Free Amination of Benzoxazoles – The First Example of an Iodide-Catalyzed Oxidative Amination of Heteroarenes

(2011) Tanja Froehr et al.   ORGANIC LETTERS

Catalytic Asymmetric Synthesis of Oxindoles Bearing a Tetrasubstituted Stereocenter at the C-3 Position

(2010) Feng Zhou et al.   ADVANCED SYNTHESIS & CATALYSIS

Metal-Free, Aerobic Dioxygenation of Alkenes Using Hydroxamic Acids

(2010) Valerie A. Schmidt et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

ipso-Nitration of Arenes

(2010) G. K. Surya Prakash et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

3-Alkenyl-oxindoles: Natural Products, Pharmaceuticals, and Recent Synthetic Advances in Tandem/Telescoped Approaches

(2010) Alessia Millemaggi et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Applications of the Chiral Auxiliaries DIOZ and TRIOZ for Conjugate Additions and Comparison with Other Auxiliaries

(2010) Hanspeter Sprecher et al.   HELVETICA CHIMICA ACTA

Iron-Mediated Radical Halo-Nitration of Alkenes

(2010) Tsuyoshi Taniguchi et al.   JOURNAL OF ORGANIC CHEMISTRY

Organocatalysis in Cross-Coupling: DMEDA-Catalyzed Direct C−H Arylation of Unactivated Benzene

(2010) Wei Liu et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

Metal-Free Highly Regioselective Aminotrifluoroacetoxylation of Alkenes

(2010) Helena M. Lovick et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

An efficient organocatalytic method for constructing biaryls through aromatic C–H activation

(2010) Chang-Liang Sun et al.   Nature Chemistry

Palladium-Catalyzed Carbo-Heterofunctionalization of Alkenes for the Synthesis of Oxindoles and Spirooxindoles

(2010) Stéphanie Jaegli et al.   ORGANIC LETTERS

Oxindole Synthesis by Direct Coupling of C sp 2H and C sp 3H Centers

(2009) Yi-Xia Jia et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

High-Oxidation-State Palladium Catalysis: New Reactivity for Organic Synthesis

(2009) Kilian Muñiz   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Oxindole synthesis by direct C–H, Ar–H coupling

(2009) Alexis Perry et al.   CHEMICAL COMMUNICATIONS

Catalytic Enantioselective Aza-Henry Reactions

(2009) Eugenia Marqués-López et al.   EUROPEAN JOURNAL OF ORGANIC CHEMISTRY

Pd-Catalyzed Conversion of Aryl Chlorides, Triflates, and Nonaflates to Nitroaromatics

(2009) Brett P. Fors et al.   JOURNAL OF THE AMERICAN CHEMICAL SOCIETY

The enantioselective intramolecular aminative functionalization of unactivated alkenes, dienes, allenes and alkynes for the synthesis of chiral nitrogen heterocycles

(2009) Sherry R. Chemler   ORGANIC & BIOMOLECULAR CHEMISTRY

Asymmetric Syntheses of Oxindole and Indole Spirocyclic Alkaloid Natural Products

(2009) Barry Trost et al.   SYNTHESIS-STUTTGART

A Selective and Practical Synthesis of Nitroolefins

(2008) Irina Jovel et al.   ADVANCED SYNTHESIS & CATALYSIS

Diastereoselective Tetrahydropyrone Synthesis through Transition-Metal-Free Oxidative Carbon–Hydrogen Bond Activation

(2008) Wangyang Tu et al.   ANGEWANDTE CHEMIE-INTERNATIONAL EDITION

Mechanistic approaches to palladium-catalyzed alkene difunctionalization reactions

(2008) Katrina H. Jensen et al.   ORGANIC & BIOMOLECULAR CHEMISTRY