4.7 Article

Stable ruthenium indenylidene complexes with a sterically reduced NHC ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 31, Pages 3188-3190

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37514a

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Funding

  1. Foundation for Polish Science Team Programme''
  2. EU European Regional Development Fund-Operational Program Innovative Economy

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Stable and active Ru olefin metathesis catalyst 7 bearing a sterically reduced NHC ligand was synthesized. Upon action of pyridine, 7 forms complex 24, the first example of an Ru-indenylidene catalyst bearing a labile pyridine ligand and a sterically less demanding NHC ligand.

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