4.7 Article

Photostability of a dyad of magnesium porphyrin and fullerene and its application to photocurrent conversion

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 3, Pages 279-281

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36988e

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Funding

  1. Funding Program for Next Generation World-Leading Researchers
  2. Japan Science and Technology Agency

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A new type of acceptor-donor(2) dyad system containing two magnesium porphyrin molecules and a fullerene molecule is much more stable than the magnesium porphyrin itself. When it is fabricated into a binary system using imidazole carboxylic acid as a linker to indium tin oxide, the molecule effects efficient photo-current generation that surpasses the device using the corresponding zinc porphyrin.

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