Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 75, Pages 8392-8394Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44549f
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Funding
- Japan Science and Technology Corporation
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- CNRS (Centre National de la Recherche Scientifique)
- Ministere de l'Education National et de la Recherche
- Agence Nationale de la Recherche
- Grants-in-Aid for Scientific Research [24105518] Funding Source: KAKEN
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The P-chirogenic organocatalysts were found to promote the enantioselective aza-Morita-Baylis-Hillman reaction of ketimines derived from acyclic alpha-keto esters. In the P-chirogenic organocatalyzed aza-MBH reactions, alpha,alpha-disubstituted alpha-amino acid derivatives were obtained in high yields with high enantioselectivities (up to 97% ee).
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