Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 76, Pages 8528-8530Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45004j
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Funding
- National Science Council of Republic of China [NSC-101-2628-M-007-004]
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An efficient synthesis of quinolizinium salts from 2-vinylpyridines and alkynes via Rh(III) or Ru(II)-catalyzed C-H activation and annulation reaction is described. A possible mechanism involving pyridine assisted vinylic ortho-C-H activation, alkyne insertion and reductive elimination is proposed.
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