4.7 Article

A functionalized MIL-101(Cr) metal-organic framework for enhanced hydrogen release from ammonia borane at low temperature

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 90, Pages 10629-10631

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc45719b

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Funding

  1. HKU Initiative on Clean Energy and Environment

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Hydrogen released from ammonia borane in MIL-101(Cr) can be significantly improved by the attached amino and amide groups. The release with minimum impurities starts at 68 degrees C, reaching 1.6 equivalent of ammonia borane at 85 degrees C for the amino modified MOFs (NH2-MIL-101).

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