4.7 Article

Electrochemical formation of MnIII-peroxo complexes supported by pentadentate amino pyridine and imidazole ligands

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 50, Pages 5696-5698

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41300d

Keywords

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Funding

  1. ANR-TAKE-CARE [ANR-2010-BLAN-0808]
  2. US NSF [CHE- 1056470, 0079282]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [0079282] Funding Source: National Science Foundation
  5. Direct For Mathematical & Physical Scien
  6. Division Of Chemistry [1056470] Funding Source: National Science Foundation

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A novel and efficient method for preparing [Mn-III(O-2)(L)](+) complexes using electrochemically generated superoxide is reported, with the reaction probed by low temperature electronic absorption and electron paramagnetic resonance spectroscopic techniques.

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