4.7 Article

Gold nanoparticle catalysis of the cis-trans isomerization of azobenzene

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 86, Pages 10073-10075

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41669k

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Funding

  1. Natural Sciences and Engineering Research Council of Canada
  2. Spanish Ministry of Economy and Competitiveness

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Ablated, pseudo-naked gold nanoparticles (AuNPs) catalyze the cis-trans isomerization of substituted azobenzenes. para-Substitution was found to affect the rate of isomerization, suggesting the participation of AuNP-mediated electron transfer in the isomerization mechanism.

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