4.7 Article

Aerobic oxidation of NHC-catalysed aldehyde esterifications with alcohols: benzoin, not the Breslow intermediate, undergoes oxidation

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 58, Pages 6513-6515

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc42597e

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Funding

  1. IRCSET
  2. Science Foundation Ireland
  3. DFG

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Benzoin (and neither the Breslow intermediate nor the NHC-aldehyde tetrahedral adduct) has been unambiguously identified as the oxidised species in aerobic NHC-catalysed aldehyde esterifications.

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