Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 28, Pages 2888-2890Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40461g
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Funding
- University of California Santa Barbara
- National Science Foundation [CHE 1059097]
- NSF [DMR 1121053]
- Direct For Mathematical & Physical Scien [1040541, 1059097] Funding Source: National Science Foundation
- Division Of Chemistry [1040541, 1059097] Funding Source: National Science Foundation
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Oxidation of [Li(THF)](2)[Co(N=(CBu2)-Bu-t)(4)] with 1 equiv. of I-2 generates Co(N=(CBu2)-Bu-t)(4) in 85% yield. In the solid-state, this complex exhibits a squashed tetrahedral structure about the Co center. DFT calculations reveal this geometry arises, in part, to maximize ketimide-to-cobalt pi-donation.
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