4.7 Article

Molecular amino-phosphonate cobalt-lanthanide clusters

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 34, Pages 3522-3524

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40907d

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Funding

  1. EPSRC (UK)
  2. University of Manchester
  3. Panamanian government agency SENACYT-IFARHU
  4. Royal Society

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The use of 1-amino-1-cyclohexyl phosphonic acid, a functionalised phosphonate, leads to the synthesis of two new structural types for 3d-4f phosphonate cages with unusual structural cores and which show high magnetocaloric effects.

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