Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 67, Pages 7409-7411Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc43663b
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The asymmetric desymmetrization of 4,6-diprotected myo-inositol derivatives was achieved by using a bifunctional, readily available nucleophilic catalyst. The orthogonally protected products were obtained in 80-99% yield with 90-99% ee. Such structures serve as potential enantiopure building blocks for the synthesis of myo-inositol phosphates.
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