4.7 Article

Functionalization of organic semiconductor crystals via the Diels-Alder reaction

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 40, Pages 4495-4497

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc40866c

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Funding

  1. NSF CAREER award [1056400]
  2. Division Of Chemistry
  3. Direct For Mathematical & Physical Scien [1056400] Funding Source: National Science Foundation

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A surface adlayer is generated on organic single crystals (tetracene and rubrene) using the site specific Diels-Alder reaction and a series of vapor phase dienophiles. X-ray photoelectron spectroscopy (XPS) confirms adsorption on the surfaces of tetracene and rubrene and mass spectrometry demonstrates the reaction's applicability to a range of dienophiles.

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