Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 46, Pages 5271-5273Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc41639a
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Funding
- National Science Centre [UMO-2011/01/N/ST5/05562]
- Foundation for Polish Science Team Programme
- European Regional Development Fund [TEAM/2011-7/8]
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We report on the activation of CO2 by the well-defined alkylzinc hydroxide (tBuZnOH)(6) in the absence and presence of tBu(2)Zn as an external proton acceptor. The slight modifications in reaction systems involving organozinc precursors enable control of the reaction products with high selectivity leading to the isolation of the mesoporous solid based on ZnCO3 nanoparticles or an unprecedented discrete alkylzinc carbonate [(tBuZn)(2)(mu(5)-CO3)](6) cluster with the Zn-C bond intact, respectively.
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