4.7 Article

Hexagonal molecular palladawheel

Journal

CHEMICAL COMMUNICATIONS
Volume 49, Issue 73, Pages 8042-8044

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c3cc44714f

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Funding

  1. Defense Threat Reduction Agency-Joint Science and Technology Office for Chemical and Biological Defense [B104283I]

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A hexagonal molecular palladawheel'' consisting of six N,N'-diphenyl-2,6-pyridinedicarboxamide-Pd(II) pincer complexes held together via six Pd center dot center dot center dot O=C-Amide bonds was efficiently synthesized and crystallographically characterized. The hexameric ring possesses C-3 (pseudo-S-6) symmetry with up-down alternating phenyl substituents acting as interior spokes and exterior propellers.

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