Journal
CHEMICAL COMMUNICATIONS
Volume 49, Issue 18, Pages 1796-1798Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36887k
Keywords
-
Categories
Funding
- Council of Chemical Sciences of The Netherlands Organization for Scientific Research (CW-NWO)
Ask authors/readers for more resources
In a microfluidic H-cell, a multi-component self-assembled system is brought out-of-equilibrium by changing the bimodal composition of porphyrin stacks and pyridine-capped dimers. Driven by their different diffusivities, diffusion-controlled separation in methylcyclohexane reveals different compositions when detected in-line and off-line, which demonstrates the kinetic behaviour of this metastable system. The microfluidic technique also proves to be highly equipped to determine diffusion constants of the different assemblies.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available